Communication: Elucidating Individual Impedance Contributions via a Versatile Reference Electrode for Lithium-Ion Batteries
Year: 2026
Type: article
Abstract: The integration of a versatile reference electrode into multi-layered pouch cells enables impedance deconvolution in lithium-ion batteries. This reference electrode facilitates isolation of impedance contributions from the cathode, anode, and full cell across a range of states of charge. The reference electrode design minimizes artefacts commonly associated with three-electrode configurations, allowing for clean impedance measurements. Fourier transform techniques were applied to reconstruct HPPC voltage responses, confirming consistency between frequency-domain and time-domain characterizations. These findings demonstrate that 3-electrode EIS with this versatile reference electrode captures transient voltage behavior at various timescales, supporting diagnostics, model calibration, and battery health monitoring.
Source: ECS Advances
Authors: Anne Zhang, Brian J. Koch, Jing Gao, Robert Taylor, Wissam Fawaz, Raneen Taha, Suryanarayana Kolluri, Taylor R. Garrick
Language: English
Subfield: Automotive Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,500
Funder: General Motors Corporation
OpenAlex ID: W7127905732