Work

Oxidation resistant cerium oxide styrene-ethylene-propylene-styrene (SEPS) composite anion exchange membranes for water electrolysis

Year: 2026

Type: article

Abstract: This study reports oxidation-resistant composite anion exchange membranes (AEMs) based on quaternised styrene–ethylene–propylene–styrene (QSEPS) ionomers reinforced with porous PTFE (1 μm pore size, 70 % porosity) and stabilised using cerium oxide (CeO 2 ) nanoparticles as regenerative radical scavengers. Ex-situ Fenton tests confirmed that CeO 2 effectively mitigates oxidative degradation, with the QSEPS/PTFE composite containing 6 wt% CeO 2 retaining 87 % of its weight after 30 h at room temperature, compared with the complete degradation of the CeO 2 -free QSEPS membrane under the same conditions. The improved stability was accompanied by a modest reduction in hydroxide conductivity in deionised (DI) water as QSEPS/CeO 2 (6 wt%)/PTFE only reached 0.035 S cm −1 at 60 °C compared with 0.048 S cm −1 for QSEPS/PTFE. However, this conductivity penalty was largely mitigated using 0.1 M KOH supporting electrolyte, where the area specific resistance (ASR) decreased from 0.339 to 0.148 Ω cm 2 for QSEPS/CeO 2 (6 wt%)/PTFE and from 0.222 to 0.115 Ω cm 2 for QSEPS/PTFE. Long-term durability tests under DI water circulation at 2 V and 60 °C showed markedly improved performance retention with QSEPS/CeO 2 (6 wt%)/PTFE exhibiting a 34.9 % current density loss over 900 h compared with 59.1 % for its CeO 2 -free counterpart, QSEPS/PTFE, corresponding to degradation rates of 147 and 314 μA cm −2 h −1 , respectively. The results demonstrate that CeO 2 nanoparticles can effectively suppress hydroxyl-radical-induced degradation, thereby extending AEM lifetime under water electrolyser conditions. • CeO 2 nanoparticles enable highly oxidation-resistant AEM composites. • QSEPS/CeO 2 /PTFE retains 87 % weight after 30 h Fenton degradation test. • Membrane durability improved twofold during 900 h water electrolysis. • CeO 2 suppresses oxidative degradation via regenerative Ce 3+ /Ce 4+ cycling. • CeO 2 stabilised AEMs offer long-life performance for alkaline electrolysers.

Source: International Journal of Hydrogen Energy

DOI: 10.1016/j.ijhydene.2026.153643

Authors: Vinothkannan Mohanraj, Hosni Ahmed Elwan, Balakondareddy Sana, Simon Doherty, Mohamed Mamlouk

Institution: Newcastle University

Language: English

Topic: Fuel Cells and Related Materials

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

SDGs: Clean water and sanitation, Affordable and clean energy

Open Access status: hybrid

Estimated APC paid: $3,730