Temperature-Dependent Pore Size Redistribution and Fractal Complexity in Low-Maturity Shale: Implications for In Situ Conversion
Year: 2026
Type: article
Abstract: Low-maturity shale is a prime target for in situ conversion (ICP), yet heating window selection remains largely empirical because pore evolution and hydrocarbon generation are rarely quantified in tandem. Nenjiang Formation shale from the Songliao Basin (TOC = 8.91%; Ro,max = 0.54%) was subjected to closed-system pyrolysis at 300–500 °C (20 °C h−1; 72 h per step). Released oil and gas and residual chloroform-extractable bitumen (“A”) were quantified, and pore evolution was characterized using 2D low-field NMR, SEM, micro-CT, and low-pressure N2 adsorption. Fractal dimensions (Ds and Dp) were derived from Frenkel–Halsey–Hill (FHH) fitting. Oil yield and bitumen “A” increased sharply above 350 °C and peaked at 375 °C, whereas gas generation accelerated above 400 °C and continued to increase to 500 °C. NMR indicates a temperature-dependent shift in retained hydrocarbons toward weaker confinement and higher mobility, with enhanced expulsion/mobility signals near 375 °C. At 375 °C, BJH pore volume and average pore diameter reached maxima (0.0675 cm3 g−1 and 15.36 nm), while Ds and Dp reached minima (2.343 and 2.444). The coincidence of peak oil expulsion with minimum fractal complexity suggests that FHH-based fractal indices provide a quantitative metric for comparing ICP heating windows in low-maturity shale.
Source: Fractal and Fractional
Authors: Qiansong Guo, Xianda Sun, Yuchen Wang, Chengwu Xu, Wei Li, Changxin He
Institution: Northeast Petroleum University
Language: English
Subfield: Mechanics of Materials
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,258
OpenAlex ID: W7130948158