Work

Potential of Wollastonite-Based Brushite Cement for the Conditioning of Radioactive Waste Contaminated by 90Sr

Year: 2026

Type: article

Abstract: This work investigates the potential of wollastonite-based brushite cement (WBC) for the stabilization and solidification of radioactive waste contaminated by 90Sr. This phosphate binder was formed by the reaction of wollastonite (CaSiO₃) with a phosphoric acid solution containing borax and metallic cations (Al3+, Zn2+). Two cement pastes were investigated: a commercial binder (WBC-C) and an optimized formulation (WBC-O), produced using a zinc-free mixing solution with a higher aluminum content than that of WBC-C. Both materials mainly contained amorphous hydrated silica and calcium aluminophosphate, along with crystalline brushite, residual wollastonite, and quartz. The stability of WBC-C under γ-irradiation was evaluated up to a dose of 1 MGy. The only observable effect was water radiolysis, leading to dihydrogen production at yields comparable to Portland cement matrices and geopolymers. Strontium leaching, assessed using the ANSI/ANS-16.1 procedure, followed a two-stage release mechanism combining surface wash-off and diffusion. The apparent diffusion coefficient Da of Sr in WBC-C was three orders of magnitude lower than typical values reported for Portland cement matrices. WBC-O showed enhanced Sr retention due to its higher aluminum content, which refines mesopores and reduces diffusion pathways accessible to Sr. WBC binders therefore appear to be promising candidates for strontium immobilization.

Source: Materials

DOI: 10.3390/ma19061136

Authors: Jihane Jdaini, Céline Cau Dit Coumes, Yves Barré, Marie-Noëlle de Noirfontaine, Mireille Courtial