Work

Sustainable Use of Portuguese Clays in Landfill Liners: Integrated Mineralogical, Chemical, and Engineering Assessment

Year: 2026

Type: article

Abstract: This study evaluated the geotechnical, mineralogical, chemical, and physico-mechanical properties of natural clays from two Portuguese regions, Aveiro and Taveiro, for their potential use as compacted landfill liners. A comprehensive set of tests was conducted, including particle size distribution, Atterberg limits, specific surface area (SSA), cation exchange capacity (CEC), swelling potential, and hydraulic conductivity (K), complemented by X-ray diffraction (XRD) and chemical composition (XRF) analyses. Results showed that Aveiro clays were predominantly fine-grained, with clay fractions exceeding 65% and high Σphyllosilicates content, particularly illite and smectite. These samples exhibited low hydraulic conductivity (K < 1 × 10−9 m/s), moderate to high plasticity, and good sealing behavior. In contrast, Taveiro clays showed greater textural variability, with higher sand content and a wider range of mineral composition, from kaolinitic to smectitic units. Selected Taveiro samples also achieved acceptable permeability values, particularly those with higher smectite content, but may require strict compaction control or blending with finer materials. The CEC and SSA measurements further distinguished the sealing potential between clay types, correlating with mineralogy and swelling capacity. The use of local clays offers potential cost savings and environmental benefits, including reduced transportation emissions and support for circular economy principles. These findings highlighted the technical viability of Portuguese clays for landfill barrier systems and underscore the importance of localized characterization for optimized liner design.

Source: Applied Sciences

DOI: 10.3390/app16062886

Authors: Carla Candeias, Fernando Rocha

Institution: University of Aveiro

Language: English

Topic: Landfill Environmental Impact Studies

Subfield: Waste Management and Disposal

Field: Environmental Science

Domain: Physical Sciences

SDGs: Responsible consumption and production, Industry, innovation and infrastructure, Sustainable cities and communities

Open Access status: gold

Estimated APC paid: $2,896