Year: 2026
Type: article
Abstract: Mineral replacement reactions under advective flow often suffer from severe spatial inefficiency: dissolution causes the flow to self-focus into a few dominant wormholes that bypass the surrounding matrix, leaving most of the rock unreplaced. Here we show—through two-dimensional pore-network simulations—that replacement can be effective in two regimes. The first arises when the precipitation rate significantly exceeds the dissolution rate, leading to in situ replacement in which a uniform front of the secondary mineral advances through the matrix. The second, exploratory mode, occurs when the system repeatedly self-blocks and re-routes. In this regime, each channel lives only long enough to deliver reactant a short distance ahead of the front before its tip is cemented by the product phase; pressure re-routes through an adjacent corridor, and the cycle begins anew. Over time, the replacement front advances as a mosaic of overlapping micro-fronts, distributing the secondary mineral almost uniformly. We derive design criteria for achieving exploratory-mode behaviour and discuss implications for both natural and engineered reactive-infiltration systems.
Source: Géotechnique Letters
Authors: A. Budek, T. Szawełło, V. Voller, P. Szymczak
Institutions: University of Minnesota, University of Warsaw
Language: English
Subfield: Environmental Engineering
Field: Environmental Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W7139135373