Work

Toward Lithium Recovery Using Modular (and Membraneless) Phase Separation and Extraction (MPSE) Technology with Ionic Liquid (IL) Solvents: Effect of Coatings

Year: 2026

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide In this work, a single-channel slope-plate modular and membraneless phase separation and extraction (MPSE) device was fabricated using 3D printing. The slope-plate was designed with an insertable glass slide to enable surface modification with coatings. Self-assembled monolayers (SAMs) and perfluoropolyether (Zdol) coatings were applied to tailor the surface wettability and enhance the phase separation. Using a model biphasic system of water and hexadecane, both coatings significantly improved the separation efficiency compared with the uncoated device by promoting selective wetting. Building on these results, lithium extraction from a simulated saline solution was investigated using 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf 2 ]) as the ionic liquid (IL) extractant. The IL effectively extracted Li + from the aqueous phase in bulk extraction, demonstrating its potential for lithium recovery. However, the low interfacial tension between the IL and aqueous phases posed challenges for phase separation. The application of SAM and Zdol coatings effectively mitigated this issue. Overall, integrating tailored surface chemistry with the slope-plate MPSE design shows great promise as an efficient and scalable platform for studying liquid–liquid separation and optimizing ionic-liquid-based extraction processes for lithium recovery from saline sources.

Source: Langmuir

DOI: 10.1021/acs.langmuir.5c06615