Year: 2026
Type: article
Abstract: XES. The work builds on our previous observation that S-XES from Mn(II) and Mn(VII) complexes pumped at high intensities can exhibit stimulated emission without sacrificing the chemical sensitivity to oxidation states. This technique opens the door to controlled high-resolution electronic structure spectroscopy in transition-metal complexes beyond the core-hole lifetime, with potential applications in catalysis, inorganic chemistry, and materials science.
Source: Physical Review Applied
DOI: 10.1103/b13n-djsx
Authors: Thomas Kroll, Margaret Doyle, Aliaksei Halavanau, Thomas M. Linker, Joshua Everts, Yurina Michine, Franklin D. Fuller, Clemens Weninger, Roberto Alonso-Mori, Claudio Pellegrini, Andrei Benediktovitch, Makina Yabashi, Ichiro Inoue, Yuichi Inubushi, Taito Osaka, Toru Hara, Jumpei Yamada, Jan Kern, Junko Yano, Vittal K. Yachandra, Nina Rohringer, Hitoki Yoneda, Uwe Bergmann
Institutions: SLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, Lawrence Berkeley National Laboratory, University of Wisconsin–Madison, Stanford University, University of Chicago, University of Electro-Communications, Linac Coherent Light Source, MAX IV Laboratory, Deutsches Elektronen-Synchrotron DESY, Center for Free-Electron Laser Science, SPring-8, RIKEN, Japan Synchrotron Radiation Research Institute, Universität Hamburg
Language: English
Subfield: Radiation
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: green
Funders: U.S. Department of Energy, National Institutes of Health, Office of Science, Japan Society for the Promotion of Science, Japan Science and Technology Agency, National Institute of General Medical Sciences, Basic Energy Sciences, Biological and Environmental Research, Precursory Research for Embryonic Science and Technology, SLAC National Accelerator Laboratory
Awards: G1229526393, G1286251239, G2371548206, G2406639143, G2561309752, G262532246, G303061748, G3055716342, G315621713, G4235786860, G4264918310, G4581610328, G495301720, G498139845, G5570207115, G6550344761, G7004986958, G7283024673, NONLINEAR X-RAY OPTICS FOR TRANSITION METAL CHEMISTRY AND COHERENT X-RAY SPECTROSCOPY, X-ray spectroscopy of Highly Reactive Catalytic Intermediates in Oxygen Activating Metallo-Enzymes, G8382000481, G8925327636, Biological Spectroscopy and Crystallography Using an X-ray Free Electron Laser, High throughput sample delivery method for time resolved studies of enzyme reactions with X-ray and complementary techniques, Taking Snapshots of Enzymatic Reactions Using X-ray Crystallography and Spectroscopy, G911061179, G969889393
OpenAlex ID: W7147150413