Work

Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions

Year: 2026

Type: article

Abstract: -configured starting materials. The discovery that noncovalent interactions can be used to guide the reactivity of excited-state DT fundamentally transforms our understanding of this reagent's control paradigms, opening the door to the design of new strategies to tune the selectivity of DT-mediated HAT steps.

Source: Journal of the American Chemical Society

DOI: 10.1021/jacs.5c22842

Authors: Huiming Liang, Jin Zhu, Leon Wang, Alison E. Wendlandt

Institution: Massachusetts Institute of Technology

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500

Funder: National Institute of General Medical Sciences