Work

Temperature dependent magnetic and structural properties of Al substituted nanostructured hexaferrites with large coercive fields

Year: 2026

Type: article

Abstract: We report a comprehensive study of the temperature-dependent structural, magnetic, vibrational, and dielectric properties of Al-substituted M-type hexaferrites SrFe 12-x Al x O 19 . Neutron powder diffraction and Mössbauer spectrometry show that Al 3+ preferentially replaces Fe 3+ at spin-up octahedral sites (2 a , 12 k ), disrupting the exchange coupling with the spin-down 4 f tetrahedral sites and leading to a progressive reduction of site-specific magnetic moments and a systematic decrease in the Curie temperature, supported by temperature-dependent susceptibility measurements. Raman spectroscopy reveals pronounced phonon anomalies near T C , particularly in modes associated with bipyramidal Fe–O vibrations, reflecting the weakening of both 4 e –12 k and 4 e –4 f exchange pathways. However, the coercive field exhibits a dramatic increase, reaching µ 0 H C ∼ 1.2 T for SrFe 9.6 Al 2.4 O 19, among the largest values reported for this class. Susceptibility measurements suggest that Al substitution, while weakening the superexchange network, contributes to the stabilization of single-domain behavior.

Source: Acta Materialia

DOI: 10.1016/j.actamat.2026.122273