Year: 2026
Type: article
Abstract: Two-dimensional (2D) indium selenide (In2Se3) has great potential for next-generation processing-in-memory applications owing to high intrinsic carrier mobility and strong ferroelectricity. However, the lack of wafer-scale, back-end-of-line (BEOL) compatible growth and inherent polarization-induced hysteresis limit their viability in logic circuits. Here, we report thermal evaporation of a non-ferroelectric κ-phase In2Se3 film that forms uniformly over 4-inch wafer-scale at <450 °C. Structural characterization confirms underexplored κ-phase formation with an indirect bandgap of 1.45 eV and n-type conduction. The unique atomic arrangement suppresses spontaneous polarization, eliminating hysteresis in field-effect transistors (FETs). The κ-In2Se3 FETs exhibit enhancement-mode operation, high field-effect mobility of 39.3 cm2 V⁻1 s⁻1, and stable switching over 1000 cycles, enabled by reduced trap states and contact resistance. By integrating κ-In2Se3 with a p-type selenium-alloyed tellurium oxide FET, we demonstrate a complementary inverter with full-swing operation and high voltage gain. These results establish κ-In2Se3 as a scalable 2D semiconductor platform for BEOL-compatible logic integration. 2D In2Se3 holds potential for 2D electronic devices, but its large-scale synthesis is challenging. The authors report the low-temperature deposition of wafer-scale non-ferroelectric κ-phase In2Se3 thin films and the fabrication of n-type transistor arrays, showing an average mobility of 39 cm2/Vs and on/off ratios of ≈108.
Source: Nature Communications
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $6,990
Funders: National Research Foundation, National Natural Science Foundation of China, National IT Industry Promotion Agency, Korea Institute of Science and Technology, Korea Institute of Science and Technology Information, National Research Foundation of Korea, Ministry of Science and ICT, South Korea
OpenAlex ID: W7159690482
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