Work

Elaboration and Solar Thermal Cycling of SiC/Al2O3/Fe–Cr–Al–Mo Multilayers

Year: 2026

Type: article

Abstract: Concentrated Solar Power (CSP) tower systems require receiver materials capable of operating above 1000 °C to meet the efficiency targets of third-generation technologies (25–30%). Hybrid solutions, combining ceramic coatings with metallic substrates, offer promising thermomechanical stability under severe thermal cycling. This study investigates the high-temperature behavior of silicon carbide (SiC) coatings deposited on Fe-C-Al-Mo alloys under concentrated solar flux. Substrates were pre-oxidized to form a continuous 1–2 µm α-Al2O3 interlayer, serving as a chemical and mechanical buffer. SiC coatings (10–24 µm thick) were deposited via High-Temperature Chemical Vapor Deposition (HT-CVD). Characterization using XRD, SEM, EDS, and optical spectrophotometry identified cubic 3C-SiC with a globular microstructure and high compressive residual stresses (−2000 to −2400 MPa), inducing microcracking. Stress relaxation was achieved by increasing coating thickness or post-deposition annealing. Controlled oxidation formed a thin silica layer, enhancing solar absorptivity to over 90%. Accelerated thermal cycling (up to ~900 kW/m2, 1050–1200 °C) revealed that coating stability depends on SiC thickness, residual stress evolution, α-Al2O3 interlayer thickness, and cycling severity. Optimizing these parameters is essential for ensuring the long-term durability of hybrid CSP receivers.

Source: Corrosion and Materials Degradation

DOI: 10.3390/cmd7020028