Work

Interfacial Chemical Selection via Post-Silanization Processing Governs Dispersion Stability of 3Y-TZP Nanoparticles: A Qualitative Assessment of Interfacial Characteristics

Year: 2026

Type: article

Abstract: This study investigated the effect of post-silanization processing on the surface chemistry and dispersion stability of 3 mol% yttria-stabilized tetragonal zirconia polycrystal (3Y-TZP) nanoparticles intended for the reinforcement of dental photopolymer resins. The nanoparticles were silanized using 3-Methacryloxypropyltrimethoxysilane and subjected to different post-treatment protocols, including control, drying, and centrifugation. Particle morphology was examined using field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). Dispersion behavior was analyzed by dynamic light scattering (DLS) and zeta potential measurements, performed in triplicate (n = 3), while surface chemical modifications were evaluated using Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). Post-silanization processing significantly influenced nanoparticle surface chemistry and dispersion stability. Centrifugation promoted the formation of Si–O–Zr and Si–O–Si linkages, reduced loosely adsorbed silane species, decreased particle agglomeration, and increased zeta potential magnitude, resulting in a more uniform hydrodynamic size distribution compared to the dried group (Z-average ≈ 814 nm, PDI ≈ 0.44). These findings suggest that post-silanization centrifugation acts as an interfacial selection mechanism that distinguishes covalently grafted silane from weakly adsorbed species. Within the limitations of this in vitro study, further investigations under varied conditions are required to confirm broader applicability.

Source: Polymers

DOI: 10.3390/polym18091089

Authors: Tunyaporn Parmornsupornvichit, Awutsadaporn Katheng, Watcharapong Tonprasong, Paweena Kongkon

Institution: Naresuan University

Language: English

Topic: Dental materials and restorations

Subfield: Orthodontics

Field: Dentistry

Domain: Health Sciences

Open Access status: gold

Estimated APC paid: $3,258

Funder: Naresuan University