Work

Achieving a Mode-Selective Optical Waveguide in a PIN-PMN-PT Single Crystal via a Nickel In-Diffusion Method

Year: 2026

Type: article

Abstract: Relaxor ferroelectric single crystals, such as Pb(In1/2Nb2/3)O3–Pb(Mg1/2Nb2/3)O3–PbTiO3, possess extraordinary electro-optic (EO) coefficients, offering immense potential for next-generation integrated modulators. However, the application of PIN-PMN-PT in fiber-optic gyroscopes (FOGs) is hindered by the challenge of fabricating high-quality optical waveguides with strict mode selectivity, as conventional diffusion typically excites multi-mode propagation. Here, the fabrication of high-quality, mode-selective waveguides is achieved in rhombohedral PIN-PMN-PT via a nickel in-diffusion technique. The resulting graded-index structures exhibit a Gaussian profile with a maximum refractive index change (∆n) of 1.53% while preserving the single crystal structure. Under specific processing conditions, we achieve precise mode selectivity, enabling exclusive transverse electric (TE) mode transmission. This mode selectivity fulfills the requirements for single-mode Y-branch geometries, establishing a robust platform for ultra-compact, low driving voltage modulators and advancing the miniaturization of inertial navigation and integrated photonic systems.

Source: Nanomaterials

DOI: 10.3390/nano16090514