Work

Novel Method of Synthesizing MoO3@MgSiO3 Nanohybrids for Decontaminating Water from Pharmaceutical Pollutants

Year: 2026

Type: article

Abstract: This work focused on synthesizing MgSiO3 (0%Mo@MgSi), 2.5%MoO3@MgSiO3 (2.5%Mo@MgSi), 5%MoO3@MgSiO3 (5%Mo@MgSi), and 10%MoO3@MgSiO3 (10%Mo@MgSi) by a single-step process utilizing butylated hydroxytoluene (BYHT) as a novel capping agent. The X-ray diffraction analysis of the synthesized nanohybrids indicated amorphous nanohybrids, while the energy-dispersive X-ray spectroscopy results illustrated variations in the MoO3 doping dosages. The 0%Mo@MgSi, 2.5%Mo@MgSi, 5%Mo@MgSi, and 10%Mo@MgSi nanohybrids exhibited average sizes of 17.6, 12.2, 11.7, and 9.9 nm, respectively, and surface areas of 43.53, 40.95, 42.17, and 44.98 m2·g−1, respectively. The examination of 0%Mo@MgSi, 2.5%Mo@MgSi, 5%Mo@MgSi, and 10%Mo@MgSi nanohybrids toward the oxytetracycline (OTC) sorption resulted in qt values of 72.89, 116.89, 98.39, and 78.46 mg·g−1, respectively. The OTC sorption onto the 0%Mo@MgSi, 2.5%Mo@MgSi, 5%Mo@MgSi, and 10%Mo@MgSi aligned with the nonlinear pseudo-second order model, and both the intraparticle and liquid-film diffusion models co-influenced the OTC sorption onto the four nanohybrids. Increasing the temperature decreased OTC sorption on 2.5%Mo@MgSi, indicating exothermic sorption. The Langmuir isotherm model was more suitable than the Freundlich model for describing OTC adsorption on 2.5%Mo@MgSi. The Dubinin–Radushkevich energy (ED ≤ 8.0 kJ·mol−1) and the Gibbs free energy (ΔG° ≤ 20 kJ·mol−1) supported each other’s outcomes about the OTC removal onto 2.5%Mo@MgSi being via physisorption. The ΔG° values increased proportionally with temperature, indicating that OTC sorption becomes more spontaneous as temperature decreases. Moreover, the 2.5%Mo@MgSi exhibited excellent stability in OTC elimination up to the third cycle.

Source: Inorganics

DOI: 10.3390/inorganics14050132