Reversible On–Off Switching of Chirality via Electrochemical Intercalation Control of Enantiopure Molecular Cations in a Layered van der Waals Material
Year: 2026
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide Manipulating chirality in materials facilitates the precise control of fascinating chirality-induced functionalities, such as chirality-induced spin selectivity (CISS) and electrical magnetochiral effect (eMChE). Recently, the intercalation of chiral molecules into layered van der Waals (vdW) materials has emerged as an effective technique for introducing chirality into materials. In particular, electrochemical methods offer a promising route for artificial chirality control, as they enable reversible ion intercalation and deintercalation via electrical manipulation. Herein, we achieve reversible on–off switching between chiral and achiral states in layered MoS 2 through the intercalation and deintercalation of a small-sized chiral cation, the ( R )/( S )-methylpyrrolidinium ion, which is smaller than the MoS 2 vdW gap. CISS and eMChE, the chirality-dependent electron transport phenomena, are used as indicators of chirality in this study. Importantly, we observe the appearance and disappearance of CISS signals in chiral molecule-intercalated and deintercalated MoS 2, respectively. These results demonstrate that combining small chiral molecular ions with layered vdW materials enables the reversible electrical control of emergent chirality-induced functionalities.
Source: ACS Nano
Authors: Po-Jung Huang, Hiroaki Kusunoki, Daisuke Nishio-Hamane, Kouji Taniguchi
Institutions: Institute of Science Tokyo, The University of Tokyo
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W7161580599