Year: 2026
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide Photocatalytic ammonia (NH 3 ) synthesis offers a carbon-neutral alternative to the Haber–Bosch process, which generates 42 million metric tons of CO 2 equivalent emissions annually. However, solar-to-ammonia conversion with contemporary photocatalysts remains far from practical requirements, and understanding the limiting factors in systems with well-defined active sites is crucial. Here, we show how the μ 3 -oxo-centered trinuclear Fe cluster in MIL-101(Fe) functions as the catalytic motif for N 2 -to-NH 3 conversion through combined experimental and computational investigations. Comparative studies with a molecular analogue demonstrate that the cluster is stabilized within the MOF framework, sustaining redox cycling and maintaining high catalytic activity. We systematically functionalized the dicarboxylate ligands of MIL-101(Fe) with −NH 2, −Br, −NO 2, −F, and −CF 3 to probe how ligand chemistry modulates Fe electron density, N 2 adsorption capacity, and proton availability, correlating these properties with catalytic performance using spectroscopic and surface characterization techniques alongside time-resolved infrared to assess excited-state lifetimes. F-functionalization optimally balances N 2 activation, proton availability at Fe active sites, and excited-state lifetimes, boosting NH 3 production by ∼ 60% relative to unmodified MIL-101(Fe). This study of ligand-functionalized MIL-101(Fe) MOFs uncovers the underlying structure-activity relationships and advances design principles for solar-driven NH 3 synthesis.
DOI: 10.1021/jacs.5c22833
Language: English
Subfield: Catalysis
Field: Chemical Engineering
Domain: Physical Sciences
SDG: Climate action
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W7161642872