High-Iodine Li(BH 4 ) 1– x I x Thin Films Enabled by Multilayer Interdiffusion and Exhibiting Stress-Assisted Conductivity Retention
Year: 2026
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide We report a vacuum-compatible multilayer interdiffusion strategy that enables controlled iodine incorporation into Li(BH 4 ) 1– x I x thin films. Alternating deposition of LiI and LiBH 4 at room temperature, followed by mild annealing at 423 K yields flat films with suppressed impurity formation and large-area compositional homogeneity. Raman spectroscopy indicates progressive stabilization of the hexagonal phase with increasing iodide content, while SEM/EDS indicates extensive interdiffusion and disappearance of multilayer boundaries, enabling high iodine compositions ( x = 0.20–0.40) that are difficult to achieve by conventional thin-film routes. AC impedance measurements reveal enhanced ionic transport below the phase-transition temperature, with a maximum room-temperature conductivity of 4.9 × 10 –5 S cm – 1 for x = 0.20 during cooling─comparable to or exceeding that of widely used thin-film electrolytes such as LiPON. In addition, a thin-film-specific conductivity retention (“memory”) effect is observed, whereby the high-conductivity state partially persists upon cooling, likely associated with interfacial constraints. This multilayer interdiffusion approach provides a general pathway for fabricating compositionally tunable hydride solid-electrolyte thin films and highlights the additional design opportunities that arise in confined thin-film geometries.
Source: ACS Omega
Authors: Erika Fukushi, Hiroyuki Oguchi
Institution: Shibaura Institute of Technology
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,935
OpenAlex ID: W7162552980