Calcium-bearing cyanopolyynes in IRC+10216
Year: 2026
Type: article
Abstract: ABSTRACT In recent years, a number of metal-containing, carbon-chain species have been detected in the external circumstellar envelope of the carbon-rich asymptotic giant branch star IRC+10216. The most common metal detected in such species is Mg, for which molecules as large as MgC$_5$N, MgC$_5$N$^+$, MgC$_6$H, and MgC$_6$H$^+$ have been observed. In this paper, we calculate the likely abundances of the Ca-bearing cyanopolyynes, CaC$_{2n+1}$N for n = 1–4, drawing the conclusion that the observed abundance of CaNC must be made from much larger Ca-terminated cyanopolyyne ions, which requires considerable rearrangement in their dissociative recombination. We pay particular attention to the detectability of CaC$_3$N whose rotational spectrum has recently been measured.
Author: T J Millar
Institution: Queen's University Belfast
Language: English
Subfield: Astronomy and Astrophysics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,046
OpenAlex ID: W7162804319
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