Work

Advanced TiO2–SiO2–Biochar Thin-Film Nanocomposite Membranes for High-Performance Removal of Dyes and Heavy Metals from Wastewater

Year: 2026

Type: article

Abstract: Next-generation wastewater treatment and recycling rely on membrane-based processes, but they face a trade-off among permeability, selectivity, and fouling resistance. In the present study, thin-film nanocomposite (TFN) membranes were fabricated by incorporating a ternary TiO2-SiO2-biochar nanofiller into a polysulfone (PSf) support using nonsolvent-induced phase separation, after which m-phenylenediamine and trimesoyl chloride were used via interfacial polymerization to produce a selective polyamide layer. The membrane compositions were M1 (22 wt.% PSf), M2 (22 wt.% PSf/0.5 wt.% TiO2/0.5 wt.% SiO2/0.5 wt.% biochar), and M3 (polyamide-coated M2). FTIR, XRD, SEM, contact-angle, porosity, and mechanical analyses supported successful membrane formation and changes in morphology, wettability, and structural strength after nanofiller incorporation and TFC coating. The addition of a nanofiller increased the hydrophilicity of the membranes by decreasing the water contact angle from 98.6 ± 0.8° for pristine PSf to 35.6 ± 1.5° for the nanocomposite membrane. Consequently, the pure-water permeability increased from 21 to 37 L m−2 h−1 bar−1. After polyamide layer formation, the optimized TFN membrane maintained a contact angle of 55.4 ± 3.8° and achieved a high Congo red rejection of 98% with permeate flux of 7–9 L m−2 h−1 bar−1. The membrane also showed good antifouling performance, with flux recovery ratios exceeding 90%. For heavy-metal-containing solutions, the optimized membrane showed apparent removal efficiencies of 78–98% for multivalent heavy metals (Pb2+, Hg2+, Cd2+, Mn2+, Zn2+, Cu2+, Ni2+, Fe3+, As3+, and Cr6+). Static adsorption tests showed the order M2 > M3 > M1, confirming that exposed TiO2-SiO2-biochar sites contribute to pollutant uptake, while the superior filtration performance of M3 is attributed to the combined effect of the polyamide selective layer and adsorption-assisted interactions. Overall, the TiO2-SiO2-biochar-based TFN membrane provides a promising platform for dye removal and preliminary heavy-metal attenuation from contaminated water.

Source: Water

DOI: 10.3390/w18121480

Authors: Muhammad Shahid Sami, Fida Hussain, Ammarah Mushtaq, Jalal Shah, Sang-Eun Oh, Aneela Anwar

Institutions: University of Engineering and Technology Lahore, Kangwon National University

Language: English

Topic: Membrane Separation Technologies

Subfield: Water Science and Technology

Field: Environmental Science

Domain: Physical Sciences

SDGs: Clean water and sanitation, Responsible consumption and production

Open Access status: gold

Estimated APC paid: $3,137