Synergistic Silk Fibroin/Cellulose Inverse Opals as Flexible Colorimetric Sensors for Multiphase Water and Organic Alcohol Recognition
Year: 2026
Type: article
Abstract: A silk fibroin/cellulose inverse-opal photonic crystal composite with robust mechanical properties was fabricated by blending a silk fibroin solution with methylcellulose, utilizing a 3D poly(methyl methacrylate) (PMMA) photonic crystal array as a template, via sequential infiltration, curing, and etching processes. Leveraging the intrinsic water sensitivity of both silk fibroin and methylcellulose, the resulting composite exhibits exceptional moisture-sensing capabilities across gaseous, liquid, and solid phases. Specifically, for atmospheric humidity, the film delivers a distinct optical response to a relative humidity variation in merely 5%. In liquid systems, owing to the material's excellent affinity for low-polarity organic solvents and the disruptive effect of highly polar solvents (e.g., water) on the photonic periodic structure, the structural color of the film can sensitively report trace water contents down to 0.025%. Furthermore, in solid matrices, the composite enables the precise detection of not only free water but also water of crystallization.
Source: Sensors
DOI: 10.3390/s26123875
Institution: Beijing Institute of Technology
Language: English
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,137
OpenAlex ID: W7165147126