Work

Stepwise C–H bond activations and assembly of binuclear Ln 3+ species coordinated by a hexaanionic anti -η 5 :η 5 -dibenzopentalene-bridged bis(carbazolyl) framework

Year: 2026

Type: article

Abstract: New binuclear complexes with a dibenzopentalene framework were obtained via spontaneous assembly in the reaction of Ln(CH 2 SiMe 3 ) 3 (THF) 2 with 3,6-di- tert -butyl-1,8-bis(phenylethynyl)-9 H -carbazole.

Source: Dalton Transactions

DOI: 10.1039/d6dt01110a

Authors: Hamza Zakaria, Gautier Félix, Dmitry M. Lyubov, Max Kallio, Veacheslav Vieru, Anna V. Vologzhanina, Rinat R. Aysin, Yannick Guari, Joulia Larionova, Alexander A. Trifonov

Institutions: Russian Academy of Sciences, G.A. Razuvaev Institute of Organometallic Chemistry, N. I. Lobachevsky State University of Nizhny Novgorod, École Nationale Supérieure de Chimie de Montpellier, Centre National de la Recherche Scientifique, Institut Charles Gerhardt Montpellier, A. N. Nesmeyanov Institute of Organoelement Compounds, Maastricht University

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: Russian Science Foundation, Université de Montpellier, Ministry of Science and Higher Education of the Russian Federation

Awards: G3122968597, G41456476, G7035165854

OpenAlex ID: W7165679696

FWCI:

Cites: 149

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Related to: 10