Work

Effects of h-BN Doping on the Microstructure, Mechanical Properties, and Dielectric Properties of Silicon Nitride Ceramics

Year: 2026

Type: article

Abstract: Silicon nitride ceramics exhibit excellent structural strength and electromagnetic wave transmission performance, yet demonstrate significant thermal shock instability under extreme conditions. Boron nitride (BN), on the other hand, possesses outstanding thermal shock resistance and electromagnetic wave transmission properties but exhibits relatively lower structural strength. Compositing these two materials holds promise for developing an integrated material that combines high-temperature load-bearing capacity with wave transmission capability. This study employed spark plasma sintering (SPS) technology to systematically investigate how varying BN content affects the sintering densification process and microstructural evolution of Si3N4/BN composite ceramics. Furthermore, we elucidated the mechanisms by which material composition and processing parameters influence key mechanical properties, dielectric characteristics, and other multifunctional attributes of the composites, providing a theoretical foundation for synergistic optimization design. The results indicate that BN incorporation suppresses both the phase transition from α-Si3N4 to β-Si3N4 during sintering and the growth of elongated β-Si3N4 crystals: the former hinders densification while the latter promotes it, resulting in a dual competitive mechanism that initially increases followed by decreases in sintered density. The effects of BN content on elastic modulus and fracture toughness align with trends in sintering density, whereas hardness, flexural strength, dielectric constant, and dielectric loss all show a monotonically decreasing trend with increasing BN content.

Source: Materials

DOI: 10.3390/ma19132775

Authors: Xia Liu, Ying Wang, Hongfei Shao, Xin Zhang, Jinyong Zhang

Institutions: Wuhan University of Technology, State Key Laboratory of Advanced Technology For Materials Synthesis and Processing

Language: English

Topic: Advanced ceramic materials synthesis

Subfield: Ceramics and Composites

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $3,137

Funder: National Natural Science Foundation of China