Year: 2026
Type: preprint
Abstract: Understanding how structural relaxation evolves from equilibrium to nonequilibrium conditions remains a central problem in glass physics. Using simulations of model glass formers under steady shear, we show that the String Model, which links stringlike cooperative rearrangements to relaxation in equilibrium glass-forming liquids, predicts the structural relaxation time across the full range of temperatures and shear rates investigated without additional nonequilibrium fitting parameters, when combined with a shear-dependent effective temperature that is captured by a generalized fluctuation-dissipation relation. These results indicate that equilibrium and nonequilibrium relaxation are governed by the same underlying cooperative mechanism, but they occur under different effective thermodynamic conditions under steady shear. More broadly, our study provides a unified microscopic description of thermal and mechanically driven dynamics in glass-forming liquids.
Source: arXiv (Cornell University)
Institution: National Institute of Standards and Technology
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
Awards: G4817222153, G5189158672
OpenAlex ID: W7169862293