Work

Vanadium Isotopic Compositions of the High‐ 3 He/ 4 He Baffin Island Lavas

Year: 2026
Type: article
Abstract: The isotopic composition of vanadium (V) in hotspot lavas provides new insight into the source of deep mantle heterogeneities. We measured V isotopic compositions in Paleogene Baffin Island lavas, which erupted above the Iceland plume head, to constrain the mantle plume source. These lavas have V isotopic compositions that are lighter (−0.96 ± 0.02‰, 2 s.e., n = 25) than most other mantle‐derived lavas (δ 51 V = −0.89 ± 0.02, 2 s.e., n = 69). This difference is statistically significant with a 99.8% confidence interval. The measured 51 V/ 50 V ratio in Baffin Island is difficult to reconcile with the assimilation of continental crust, fractional crystallization, crystal accumulation, isotopic fractionation during mantle melting, or the recycling of sediments. Possibly, the Baffin Island lavas sample an ancient (>3 Ga) melt‐depleted mantle reservoir. However, this cannot explain the similarly low 51 V/ 50 V measured in younger lavas related to the Iceland plume. Instead, the V isotopic composition of Baffin Island lavas may be consistent with the incorporation of core‐affected material into the Iceland plume. The advection of bulk core into the lowermost mantle is improbable, so we hypothesize that, if the V isotopic difference is due to core‐mantle interactions, V partitioned into core‐exsolved oxides that imparted a core‐like V isotopic composition on the Baffin Island mantle source.
Language: English
Open Access status: gold
Estimated APC paid: $3,000
OpenAlex ID: W7202076788
FWCI:
Cites: 67
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Related to: 10