Work

Nutrient Removal by Halloysite-Amended Mineral Matrices and Heavy Metal Retention in Rain Gardens Under Dynamic Hydraulic Flow Conditions

Year: 2026

Type: article

Abstract: Rain gardens are widely used for stormwater treatment; however, the performance of alternative sorbent materials under varying rainfall conditions remains insufficiently understood. In this study, the removal of nutrients and heavy metals was evaluated in laboratory-scale rain gardens amended with halloysite of two grain size fractions (1–2 mm and 2–4 mm) under rainfall events lasting 30 and 120 min. Three column systems were tested: a reference column containing dolomite, sand, and gravel (C1), and two halloysite-amended columns (C2 and C3). Synthetic stormwater containing N–NH4+, N–NO3–, P–PO43–, Cu, Zn, and Pb was applied. Halloysite improved nutrient removal in all rainfall scenarios compared with the reference column. Dissolved inorganic nitrogen (DIN) removal reached 84% in column C3, whereas soluble reactive phosphorus (SRP) removal reached 85% in column C2. Complete removal of Cu, Zn, and Pb was observed in all columns, highlighting the dominant role of dolomite in heavy metal retention. These findings demonstrate the potential of halloysite as a nutrient-removing amendment in rain garden.

Source: Materials

DOI: 10.3390/ma19163466

Authors: Agnieszka Grela, Justyna Pamuła, Karolina Łach, Maciej Thomas, Damian Grela

Institution: Cracow University of Technology

Language: English

Topic: Urban Stormwater Management Solutions

Subfield: Environmental Engineering

Field: Environmental Science

Domain: Physical Sciences

SDGs: Clean water and sanitation, Responsible consumption and production, Zero hunger

Open Access status: gold

Estimated APC paid: $3,137