High-pressure/high-temperature synthesis of Cr(PO 4 )·H 2 O
Year: 2026
Type: article
Abstract: The new chromium(III) phosphate monohydrate Cr(PO 4 )·H 2 O has been synthesized in a Walker-type module under high-pressure/high-temperature conditions of 9 GPa and 1,000 °C. It crystallizes in the monoclinic space group P 2 1 / n (no. 14) with the cell parameters a = 6.1986(3) Å, b = 8.0938(3) Å, c = 6.2494(2) Å, β = 91.661(2)°, V = 313.40(2) Å 3 and Z = 4. Cr(PO 4 )·H 2 O possesses a novel nesophosphate structure with units of two edge-sharing CrO 5 (H 2 O) octahedra.
Source: Zeitschrift für Naturforschung B
Authors: Anastasiia Shagova, Michael Seidl, Hubert Huppertz
Institution: Universität Innsbruck
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $2,712
OpenAlex ID: W7204185269