Work

Copper Smelting Slag-Derived Fe3O4@Mesoporous Silica for Peroxymonosulfate Activation and Tetracycline Degradation: Performance, Mechanism, and Life Cycle Assessment

Year: 2026

Type: article

Abstract: Tetracycline (TC) is a widely used antibiotic that is frequently detected in rivers, lakes and wastewater. Because TC is poorly removed by conventional biological treatment, its residues can harm aquatic organisms and promote the spread of antibiotic resistance; efficient and low-cost technologies for removing TC from water are therefore needed. In this study, copper smelting slag (CSS), an abundant industrial solid waste, was converted into a catalyst composed of Fe3O4 particles loaded on mesoporous silica (denoted Fe3O4@MS) via an alkali fusion–hydrothermal method. The catalyst was used to activate peroxymonosulfate (PMS), forming the Fe3O4@MS/PMS treatment system for the degradation of TC in aqueous solution. The effects of the main operating parameters (catalyst dosage, PMS concentration, initial pH and reaction temperature) on TC degradation were systematically evaluated. Under the optimized conditions (catalyst 0.5 g/L, PMS 1.0 mmol/L, initial pH 6.5, 25 °C), the Fe3O4@MS/PMS system removed 98.70% of 50 mg/L TC within 60 min. Radical quenching experiments and electron paramagnetic resonance (EPR) analysis revealed that TC was degraded through both radical pathways (hydroxyl •OH, sulfate SO4•− and superoxide O2•− radicals) and a non-radical pathway involving singlet oxygen (1O2), with •OH being the dominant reactive species. Nine degradation intermediates were identified by liquid chromatography–mass spectrometry (LC-MS), based on which three degradation pathways were proposed. Toxicity estimation indicated that ring-opening and deamination reactions are the key steps for detoxification. In addition, a life cycle assessment (LCA) across five selected impact categories identified the main environmental burdens associated with catalyst production. Overall, this work demonstrates that CSS-derived Fe3O4@MS is an efficient, low-cost and sustainable catalyst for PMS-based antibiotic removal from water, offering a circular-economy approach that couples solid-waste valorization with clean water production.

Source: Toxics

DOI: 10.3390/toxics14090757