Work

Reactivity of a phosphaalumene towards heteroallenes

Year: 2026

Type: article

Abstract: TerP(H)C(NHiPr)NiPr (7) with the concomitant formation of a trimeric aluminoxan. This study demonstrates the potential of phosphaalumene 1 as a synthon for aryl phosphaketenes, which themselves enable the synthesis of novel heterocyclic structures. Moreover, the reactivity towards DIC differs considerably from that of related phosphagallenes, enabled by the lability of the Al-Cp* bond.

Source: Chemical Science

DOI: 10.1039/d6sc04181g

Authors: Tim Wellnitz, Jakob Boardman, Paul Fritsche, Yannick Konrad, Diana Bröllos, Samuel Nees, Holger Braunschweig, Christian Hering-Junghans

Institutions: University of Würzburg, Leibniz Institute for Catalysis

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funder: Deutsche Forschungsgemeinschaft

OpenAlex ID: W7204760120

FWCI: 1.174

Cites: 44

Cited by: 1

Related to: 10