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Solvent-free isomerization of trialkoxy-heptazine derivatives featuring efficient intermolecular rearrangements

Year: 2025

Type: article

Abstract: Trialkoxy-heptazine, Hz(OR) 3 , undergoes efficient isomerization to trialkylheptazine-trione, HzTO-R 3 , under solvent-free conditions via intermolecular rearrangements, offering potential for stimuli-responsive material development.

Source: Materials Chemistry Frontiers

DOI: 10.1039/d5qm00246j

Authors: Barun Dhara, Mengwen Yan, Ryotaro Ibuka, Jiaxian Wang, Atsuko Nihonyanagi, Hiroyuki Inuzuka, Yuko Hamada, Toshie Wakamatsu, Kiyohiro Adachi, Daisuke Hashizume, Norihito Fukui, Daigo Miyajima

Institutions: RIKEN Center for Emergent Matter Science, Chinese University of Hong Kong, Chinese University of Hong Kong, Shenzhen, Integrated Research Consortium on Chemical Sciences, Nagoya University, Nagoya University

Language: English

Topic: Photochromic and Fluorescence Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funders: Japan Science and Technology Corporation, National Natural Science Foundation of China, Shenzhen Science and Technology Innovation Program

Awards: G478847963, G5990948901, G7057487687

OpenAlex ID: W4411238821

FWCI:

Cites: 41

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Related to: 10