Work

The atomic C/O ratio of KELT-9b

Year: 2026
Type: article
Abstract: Context . The carbon-to-oxygen (C/O) ratio of a giant planet’s atmosphere has long been theorised to hold compositional information that can be traced back to its formation history. Typically, the C/O ratio of an exoplanetary atmosphere is inferred from abundance measurements of major C- and O-bearing molecules such as CO, CO 2 , H 2 O, and OH. However, some exoplanets have such elevated temperatures that molecules can be nearly completely thermally dissociated at the pressure levels that observations probe, making it difficult to measure their C/O ratio via these traditional tracers. Aims . Here, rather than using molecules, we aim to retrieve the C/O ratio of KELT-9b (T eq = 4000 K) directly from atomic C and O, which are detected in its atmosphere. Methods . We analysed two transits of KELT-9b observed with the MAROON-X high-resolution spectrograph, finding absorption cross-correlation signals from atomic C and O as well as refractory metals. From this, we inferred the vertical temperature structure, the relative proportions of volatile and refractory species, and the C/O ratio of KELT-9b using a 1D local thermodynamic equilibrium atmospheric retrieval framework applied only to spectral regions mostly unaffected by non-local thermodynamic equilibrium effects. Results . We measure the atomic C/O ratio of the atmosphere of KELT-9b to be 0.20 −0.07 +0.13 , which is slightly lower than the stellar value of 0.38 ± 0.15 and significantly below the solar value of 0.59 ± 0.07. We otherwise confirm previous investigations of the terminator region, finding KELT-9b’s atmosphere to be thermally inverted and slightly metal-rich. We measure the volatile-to-refractory ratio, a proxy for the ice-to-rock ratio, to be 1.24 −0.78 +1.93 × solar ([M vol /M ref ] = 0.09 −0.20 +0.19 ), which is consistent with both KELT-9 and the Sun. Conclusions . While there are caveats to interpreting observations of such an extreme planet, our results demonstrate that atomic species can be used to measure C/O ratios of exoplanetary atmospheres in high-temperature regimes where molecules are thermally dissociated.
Language: English
Open Access status: gold
Estimated APC paid: $1,865
OpenAlex ID: W7213080412
FWCI:
Cites: 144
Cited by:
Related to: 10