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Oxygen-enabled Fe-catalyzed heteroatom α-C(sp 3 )–H functionalization with nucleophiles

Year: 2026
Type: article
Abstract: Here, we report an iron-catalyzed aerobic transformation that activates N/O/S-α-C(sp 3 )–H bonds under blue light irradiation, forming hemiacetal-like intermediates, amenable for trapping with diverse commercially available nucleophiles.
DOI: 10.1039/d6sc05655e
Authors: Xinlong Zhou, Jiayin Li, Nan Huang, Jingjing Zhao, Baokun Qiao, Hegui Gong, Pan Li
Institution: Henan University
Language: English
Field: Chemistry
Open Access status: diamond
OpenAlex ID: W7213562724
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