Year: 2026
Type: preprint
Abstract: Raman spectroscopy is widely used for molecular identification in biological samples, but spectral congestion often obscures key molecular fingerprints. Strategies to enrich vibrational spectra with additional controllable features are therefore desirable. We theoretically show that vibrational strong coupling (VSC) can reshape Raman spectra by reorganizing vibrational energies and intensities. Near-resonant coupling enables the resolution of quasi-degenerate vibrational modes and redistributes Raman activity among molecular vibrations, brightening otherwise Raman-inactive modes. Off-resonant coupling mediates effective interactions between vibrations, leading to tunable intensity reorganizations and spectral shifts via cavity-controlled vibrational mixing. Using a microscopic theory of Raman scattering, we show that observing Raman signals from collective VSC polaritons requires appropriate geometries for the scattering setup, the sample, and the cavity environment, helping to explain why polaritonic Raman signatures have remained challenging to observe experimentally.
Source: arXiv (Cornell University)
Institution: Technical University of Denmark
Language: English
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: green
Award: G1904433944
OpenAlex ID: W7213938312