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Statistical thermodynamics of the quantum spin-s XXZ Heisenberg model in the Weiss limit

Year: 2026
Type: article
Abstract: The statistical thermodynamics of the quantum spin- s XXZ Heisenberg model in the Weiss (mean-field) limit rests on the outer multiplicities of the irreducible representations in the Clebsch–Gordan decomposition of the n -fold spin- s tensor product, which determine the energy-level degeneracies and hence the partition function. Using known closed forms for these multiplicities in terms of generalized binomial coefficients of order 2 s + 1 , we write the exact finite-size partition function of the effective collective Hamiltonian and evaluate its thermodynamic limit by a large-deviation (Laplace) analysis validated against direct summations for systems of up to n = 10 4 spins. The free energy then follows from a two-parameter variational principle in the total spin and the magnetization per site. The ferromagnetic ordering is driven by the rotationally invariant part of the Hamiltonian, so that the Curie temperature T c = 1 3 J s ( s + 1 ) is independent of the anisotropy Δ, and the transition is of second order for every spin s , with classical mean-field exponents. The anisotropy reshapes the phase diagram: for Δ < 1 the field-driven first-order line of the isotropic ( Δ = 1 ) model opens into a dome of easy-plane ferromagnetic order, bounded by a continuous transition that restores the residual U(1) symmetry, and no first-order transitions or metastability occur throughout − 1 ≤ Δ < 1 ; the isotropic Curie-Weiss ferromagnet is recovered as Δ → 1. In two appendices we detail the asymptotics of the outer multiplicities down to the Gaussian-fluctuation prefactor and discuss the q -number and Jacobi-theta structures underlying the model, including the partial-theta-type structure that obstructs a standard theta-function reduction of the residual total-spin sum.
Language: English
Open Access status: diamond
OpenAlex ID: W7220911061
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Cites: 46
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Related to: 10