Work

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS)

Year: 2026
Type: article
Abstract: Context . Methyl cyanide (CH 3 CN) is one of the most abundant nitrogen-bearing complex organic molecules observed in the gas phase around both low- and high-mass protostars. However, very few observations exist with a broad enough frequency coverage and sufficiently high sensitivity to systematically characterize its minor isotopologues toward such regions. Aims . We add to this number by analyzing data toward BHR71-IRS1 taken with the Atacama Large Millimeter/submillimeter Array (ALMA) as part of the Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) Large Program over a ∼33 GHz frequency range. Methods . We studied as many isotopologues of methyl cyanide as possible toward BHR71-IRS1. We found the column densities and excitation temperatures via spectral fitting and assuming local thermodynamic equilibrium. We then compared the derived column density ratios with those toward IRAS 16293-2422 A and B, V883 Ori, G31.41+0.31, and Sgr B2(N2b). Results . We detect CH 3 CN, CH 3 CN v 8 =1, 13 CH 3 CN, CH 3 13 CN, CH 3 C 15 N, CH 2 DCN, and CHD 2 CN. The column density ratio of 13 CH 3 CN/CH 3 13 CN is around unity, in agreement with previous observations. The CH 2 DCN/CH 3 CN ratios are similar for all the low-mass objects but are ∼1 order of magnitude higher than those toward Sgr B2(N2b). This could be due to a warmer pre-stellar phase or a different formation timescale of Sgr B2(N2b). Conclusions . The D/H ratios found from methyl cyanide isotopologues agree well with those of methanol toward BHR71-IRS1, likely pointing to the formation and deuteration of methyl cyanide in a similar star-formation phase as methanol (i.e., the pre-stellar phase). We find an increase in the methyl cyanide D/H ratios with the number of deuterium atoms, which suggests that the deuterated isotopologues may form later in the pre-stellar phase. Future COMPASS studies will increase the sample size of low-mass systems with methyl cyanide analysis and potentially examine some of the trends observed here statistically.
Language: English
Open Access status: gold
Estimated APC paid: $1,865
OpenAlex ID: W7220834962
FWCI: 2.428
Cites: 92
Cited by: 1
Related to: 10