Work

A difluoroboryl radical and its boryl anion

Year: 2026

Type: article

Abstract: A cyclic alkyl(amino)carbene-stabilised trifluoroborane can be reduced stepwise to the corresponding stable and boron-centred difluoroboryl radical and boryl anion nucleophile.

Source: Chemical Science

DOI: 10.1039/d6sc05302e

Authors: Eduardo F. S. Guimarães, Andreas Sachs, Johannes Röder, Sophia M. Schalk, Lea Völker, Lenja Wilkens, Merle Arrowsmith, Ivo Krummenacher, Sourav Kar, Eufrânio N. da Silva Júnior, Holger Braunschweig

Institutions: Universidade Federal de Minas Gerais, University of Würzburg

Language: English

Topic: Organoboron and organosilicon chemistry

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Alexander von Humboldt-Stiftung, Deutscher Akademischer Austauschdienst, Deutsche Forschungsgemeinschaft, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Conselho Nacional de Desenvolvimento Científico e Tecnológico

Awards: G2346257781, 500 MHz NMRSpektrometerkonsole, G6815844370

OpenAlex ID: W7221113842

FWCI:

Cites:

Cited by:

Related to: 10