Precursor-Concentration-Regulated CuO-CeO2 Catalysts with Tailored Oxygen Species and Redox Behavior for Efficient C3H6 Catalytic Combustion
Year: 2026
Type: article
Abstract: Flame synthesis is a promising route for producing mixed-oxide catalysts, but the role of precursor concentration in regulating catalyst formation during self-sustained flame pyrolysis remains insufficiently understood. In this work, CuO-CeO2 mixed-oxide catalysts were prepared by varying the total metallic precursor concentration from 0.04 to 0.28 mol·L−1 while keeping the Cu/(Cu + Ce) molar ratio fixed at 35 mol.%. This strategy enables the influence of precursor concentration to be distinguished from that of metal composition and provides insight into the formation of CuO-CeO2 catalysts under a self-sustained flame environment. The results show that precursor concentration strongly affects particle aggregation, crystallite growth, Cu species distribution and possible lattice incorporation, oxygen species distribution, and low-temperature reducibility. Among the prepared catalysts, CuCe0.20 exhibits the most favorable balance among textural characteristics, Cu-Ce interaction, oxygen species distribution and redox behavior, and surface reactive oxygen availability. As a result, CuCe0.20 achieves 90% C3H6 conversion at 380 °C and nearly complete conversion at 450 °C. More importantly, it maintains stable activity during a 600 min test at 450 °C with an apparent CO2 selectivity of 99.9%. Post-reaction characterization further reveals that the CeO2 framework and Cu-Ce interaction are largely retained, while the relative contribution of lattice oxygen increases after long-term reaction, accompanied by retained low-temperature reducibility. This work extends the design of flame-made CuO-CeO2 catalysts from composition optimization to precursor-concentration engineering and demonstrates a practical strategy for preparing stable non-noble metal catalysts for VOC catalytic combustion.
Source: Molecules
Institution: Southeast University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,258
Award: G9001174731
OpenAlex ID: W7221594263