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A super-bulky phosphanide ligand enables the observation of scalar coupling between 31 P and 7 Li, 23 Na, 85 Rb/ 87 Rb, and 133 Cs

Year: 2026

Type: article

Abstract: A full set of alkali metal complexes of a super-bulky phosphanide ligand was synthesised. These compounds enable observation by NMR spectroscopy of scalar coupling between 31 P and heavier alkali metal nuclei for the first time.

Source: Dalton Transactions

DOI: 10.1039/d6dt02307j

Authors: Ahmed Hadadi, Corinne Y. Wills, Casey M. Dixon, Paul G. Waddell, Keith Izod

Institutions: Imam Mohammad ibn Saud Islamic University, Newcastle University

Language: English

Topic: Advanced NMR Techniques and Applications

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Al-Imam Muhammad Ibn Saud Islamic University, National Institutes of Health, National Institute of General Medical Sciences, National Institute of Allergy and Infectious Diseases

Award: ChimeraX -- Next Generation Visualization and Analysis Software for Multiscale Modeling

OpenAlex ID: W7223152674

FWCI:

Cites: 99

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Related to: 10