Pulsed hyperfine EPR study of formally divalent rare earth (scandium, yttrium, lanthanum) arene complexes
Year: 2026
Type: article
Abstract: }), supported by DFT, reveals extensive delocalisation of spin density to the arene ring bound to the metal (56-73% Mulliken spin population, 42-53% Löwdin orbital population of SOMO, from DFT). Hence, they are RE(II) complexes in a formal sense only.
Source: Chemical Communications
DOI: 10.1039/d6cc06362d
Institution: University of Manchester
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Awards: EPR NRF Capital Award for Core Equipment 2024/25, G5092458911, DTP 2224 University of Manchester, G713447445, DTP 2020-2021 The University of Manchester, EPR NRF Core Equipment Bid, Capital Award for Core Equipment 2022/23, National Research Facility for Electron Paramagnetic Resonance Spectroscopy, G8912375032, A National Research Facility for EPR Spectroscopy, 2022-2027
OpenAlex ID: W7223176955