Work

Hydrogenolysis triggered formation of zero-valent metals and metal selenides at room temperature from divalent metal aminoxide complexes facilitated by metal-ligand cooperativity

Year: 2026

Type: article

Abstract: P and 2,2,6,6-tetramethylpiperidin-1-ol (TEMPOH). Our studies suggest that an MLC-mediated hydrogenolysis reactivity pathway can be leveraged to furnish putative transient metal-hydride species, and such species could serve as zero-valent metal synthons for binary material synthesis.

Source: Chemical Science

DOI: 10.1039/d6sc07403k

Authors: Lina M. Zarnitsa, Oliver E. Garcia, Martin-Louis Y. Riu, Allison Lorber, Miguel Medina Lopez, Anneke Talke, Tyler A. Kerr, Matthew Nava

Institution: University of California, Los Angeles

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, National Institutes of Health, University of California, Los Angeles, Office of Research Infrastructure Programs, National Institutes of Health, California NanoSystems Institute

Award: CAREER: Metal Ligand Cooperativity to Cleave C-H Bonds

OpenAlex ID: W7223866863

FWCI:

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