Work

Biasing the dynamic Δ / Λ equilibrium of a helical and luminescent Tb( iii ) complex on chiral amine-functionalized silica surfaces

Year: 2026

Type: article

Abstract: A chiral 1-phenylethylamine-functionalized SiO 2 surface biases the Δ / Λ equilibrium of a racemic luminescent Tb( iii ) (cyclen) complex and induces CD and CPL. Calculations suggest preferential Δ and Λ forms on the ( R )- and ( S )-surfaces, respectively.

Source: Chemical Science

DOI: 10.1039/d6sc04846c

Authors: Sora Shirai, Satoshi Muratsugu, Keiko Hibi, Naoki Yokoyama, Hisaki Matsui, Takafumi Shiraogawa, Masahiro Ehara, Hidetaka Nakai, Mizuki Tada

Institutions: Nagoya University Research Center for Materials Science, Integrated Research Consortium on Chemical Sciences, Nagoya University, Nagoya University, Kindai University, Institute for Molecular Science, Research Center for Computational Science

Language: English

Topic: Lanthanide and Transition Metal Complexes

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: Ministry of Education, Culture, Sports, Science and Technology, Nagoya University, Japan Society for the Promotion of Science

Awards: G114881165, G2910566145, G3415956203, G3894111080, G4424742155, G4503683568, G460159371, G619523994, G7170099068, G7261116566, G8108278755, G8555837583, G8819573156

OpenAlex ID: W7224109860

FWCI:

Cites: 50

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Related to: 10