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Syun‐ichi Kiyooka

Observed names: SYUN'ICHI KIYOOKA, SYUN‐ICHI KIYOOKA, Syun-ichi KIYOOKA, Syun-ichi Kiyooka, Syunichi Kiyooka, Syun’ichi Kiyooka
Observed institutions: Kyushu University, University of Kochi, Osaka City University, Ehime University, Otsuka Pharmaceutical Factory (Japan), Institute for Materials Chemistry and Engineering, Kyushu University, Kōchi University, University of California, Berkeley
OpenAlex ID: A5111767307
Enantioselective chiral borane-mediated aldol reactions of silyl ketene acetals with aldehydes. The novel effect of the trialkysilyl group of the silyl ketene acetal on the reaction course
1991 · Syunichi Kiyooka, Yuichi Kaneko, et al. · The Journal of Organic Chemistry · 195
1,3-syn diastereoselective reduction of β-hydroxyketones with diisobutylaluminum hydride and tributyltin hydride
1986 · Syun-ichi Kiyooka, Hisanori Kuroda, et al. · Tetrahedron Letters · 127
The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditions
1992 · Syun-ichi Kiyooka, Yuichi Kaneko, et al. · Tetrahedron Letters · 117
Acyclic stereoselection. 22. Diastereofacial selectivity in the Lewis acid mediated reactions of allylsilanes with chiral aldehydes and enones
1984 · Clayton H. Heathcock, Syunichi Kiyooka, et al. · The Journal of Organic Chemistry · 102
A Study Directed to the Asymmetric Synthesis of the Antineoplastic Macrolide Acutiphycin under Enantioselective Acyclic Stereoselection Based on Chiral Oxazaborolidinone-Promoted Asymmetic Aldol Reactions
1999 · Syun-ichi Kiyooka, Mostofa A. Hena · The Journal of Organic Chemistry · 77
Parr’s index to describe both electrophilicity and nucleophilicity
2012 · Syun-ichi Kiyooka, Daisuke Kaneno, et al. · Tetrahedron Letters · 67
[IrCl(cod)]2-catalyzed direct oxidative esterification of aldehydes with alcohols
2007 · Syun-ichi Kiyooka, Yosuke Wada, et al. · Tetrahedron · 59
A mild aldol reaction of aryl aldehydes through palladium-catalyzed hydrosilation of α,β-unsaturated carbonyl compounds with trichlorosilane
1998 · Syun-ichi Kiyooka, Atsushi Shimizu, et al. · Tetrahedron Letters · 59
Intrinsic reactivity index as a single scale directed toward both electrophilicity and nucleophilicity using frontier molecular orbitals
2013 · Syun-ichi Kiyooka, Daisuke Kaneno, et al. · Tetrahedron · 55
Dramatic changes in diastereoselectivity with the quantity of titanium tetrachloride used in Lewis acid mediated reactions of allylsilane with .alpha.-amino aldehydes
1989 · Syunichi Kiyooka, Masahito Nakano, et al. · The Journal of Organic Chemistry · 51
Enantioselective construction of nitrogen-substituted quaternary carbon centers adjacent to the carbonyl group in the cyclohexane ring: first asymmetric synthesis of anesthetic (S)-ketamine with high selectivity
2009 · Reiko Yokoyama, Satoshi Matsumoto, et al. · Tetrahedron · 46
Acyclic stereoselection. 20. High diastereofacial selectivity in the stannic chloride mediated reactions of allylsilanes with chiral α- and β-alkoxy aldehydes.
1983 · Syun-ichi Kiyooka, Clayton H Heathcock · Tetrahedron Letters · 46
Enantioselective acyclic stereoselection under catalyst control—III. A very short asymmetric synthesis of the bryostatin C1C9 segment using the chiral oxazaborolidinone-promoted aldol reaction
1997 · Syun-ichi Kiyooka, Hirofumi Maeda · Tetrahedron Asymmetry · 44
Iridium-catalyzed oxidative esterification reaction of aliphatic aldehydes and olefinic alcohols with precoordination of the double bond of alcohols to iridium
2005 · Syun-ichi Kiyooka, Mahuyu Ueno, et al. · Tetrahedron Letters · 42
Direct enantioselective synthesis of syn-1,3-diols by the reaction of aldehydes with enol silyl ethers in the presence of a chiral borane complex. Successive asymmetric aldol reaction and asymmetric reduction with one promoter
1994 · Yuichi Kaneko, Takao Matsuo, et al. · Tetrahedron Letters · 41
A novel nitroaldol reaction catalyzed by rhodium complex in the presence of a silyl ketene acetal
1995 · Syun-ichi Kiyooka, Takanori Tsutsui, et al. · Tetrahedron Letters · 38
Regulated-Stereoselective Construction of Thirteen Stereogenic Centers Necessary for the Frame of (+)-Discodermolide, Based on Iterative Lewis Acid-Promoted Aldol Reactions
2003 · Syun-ichi Kiyooka, Kazi Abdus Shahid, et al. · The Journal of Organic Chemistry · 36
First general synthesis of monosilyl acetals. Trimethylsilyl trapping of the intermediate in DIBALH reduction of carboxylic acid esters using trimethylsilyl trifluoromethanesulfonate
1993 · Syun-ichi Kiyooka, Masashi Shirouchi, et al. · Tetrahedron Letters · 36
Catalyst control in a chiral borane-mediated aldol reaction. Both syn- and anti-aldols in almost optically pure state obtained from one racemic aldehyde
1996 · Syun-ichi Kiyooka, Haruhide Kira, et al. · Tetrahedron Letters · 35
A Novel BF3.cntdot.OEt2-Catalyzed [3 + 2] Annulation of N-Cbz-.alpha.-Amino Aldehydes with Allyltrimethylsilane. Highly Stereoselective Synthesis of Cis-2,3,5-Trisubstituted Pyrrolidines
1994 · Syun-ichi Kiyooka, Yasuhiro Shiomi, et al. · The Journal of Organic Chemistry · 35
Photochemical intramolecular cyclization reactions of acylgermanes
1990 · Syunichi Kiyooka, Yuichi Kaneko, et al. · The Journal of Organic Chemistry · 35
Boron trifluoride promoted aldol reaction of silyl ketene acetals with the intermediate generated by the DIBALH reduction of carboxylic acid esters
1992 · Syunichi Kiyooka, Masashi Shirouchi · The Journal of Organic Chemistry · 32
An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions
2000 · Syun-ichi Kiyooka, Mostofa A Hena, et al. · Tetrahedron Letters · 31
A chiral oxazaborolidinone-promoted aldol reaction with a silyl ketene acetal from ethyl 1,3-dithiolane-2-carboxylate. Synthesis of acetate aldols in high enantiomeric purity
1996 · Syun-ichi Kiyooka, Mostofa Abu Hena · Tetrahedron Asymmetry · 30
Enantioselective acyclic stereoselection under catalyst control. 2.1 Asymmetric synthesis of syn- and anti-1,3-diols incorporating an acetate equivalent by the chiral oxazaborolidinone-catalyzed aldol reaction
1997 · Syun-ichi Kiyooka, Takafumi Yamaguchi, et al. · Tetrahedron Letters · 29
Works count: 105
Citation count: 2,191
H-index: 26
I10-index: 61
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