Keyword

aryne insertion

Description: An organic reaction in which an aryne inserts into a chemical bond, enabling formation or expansion of molecular frameworks.

Primary topic: Cyclization and Aryne Chemistry (90%)

OpenAlex ID: keywords/aryne-insertion

Palladium-Catalyzed Intermolecular Controlled Insertion of Benzyne-Benzyne-Alkene and Benzyne-Alkyne-Alkene—Synthesis of Phenanthrene and Naphthalene Derivatives

2000 · Eiji Yoshikawa, Yoshinori Yamamoto · Angewandte Chemie International Edition · 160

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Aryne Insertion Reactions into Carbon-Carbon σ-Bonds

2012 · Hiroto Yoshida, Ken Takaki · Synlett · 140

Activation of Aryl Thiocyanates Followed by Aryne Insertion: Access to 1,2-Thiobenzonitriles

2015 · Martin Pawliczek, Lennart K. B. Garve, et al. · Organic Letters · 133

Insertion of Arynes into Thioureas: A New Amidine Synthesis

2011 · Kallolmay Biswas, Michael F. Greaney · Organic Letters · 95

Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes

2013 · Hiroto Yoshida, Ryuma Yoshida, et al. · Angewandte Chemie International Edition · 89

Palladium‐Catalyzed CS Activation/Aryne Insertion/Coupling Sequence: Synthesis of Functionalized 2‐Quinolinones

2014 · Ying Dong, Bangyu Liu, et al. · Angewandte Chemie International Edition · 86

Aryne insertion into α-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons

2005 · Hiroto Yoshida, Masahiko Watanabe, et al. · Tetrahedron Letters · 85

Synthetic Applications and Methodological Developments of Donor−Acceptor Cyclopropanes and Related Compounds

2016 · Nicholas R. O'Connor, John L. Wood, et al. · Israel Journal of Chemistry · 83

Aryne Insertion Reactions Leading to Bioactive Fused Quinazolinones: Diastereoselective Total Synthesis of Cruciferane

2013 · Sagar D. Vaidya, Narshinha P. Argade · Organic Letters · 81

Straightforward construction of diarylmethane skeletons via aryne insertion into carbon–carbon σ-bonds

2007 · Hiroto Yoshida, Masahiko Watanabe, et al. · Chemical Communications · 81

Palladium‐Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines

2008 · Thibaud Gerfaud, Luc Neuville, et al. · Angewandte Chemie · 80

Aryne Acyl-Alkylation in the General and Convergent Synthesis of Benzannulated Macrolactone Natural Products: An Enantioselective Synthesis of (−)-Curvularin

2010 · Pamela M. Tadross, Scott C. Virgil, et al. · Organic Letters · 76

Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides

2017 · Xiaojin Li, Yan Sun, et al. · Organic Letters · 72

Aryne Insertion into I–I σ-Bonds

2012 · Diego Rodríguez-Lojo, Agustín Cobas, et al. · Organic Letters · 70

Versatile Route to Benzoannulated Medium-Ring Carbocycles via Aryne Insertion into Cyclic 1,3-Diketones: Application to a Synthesis of Radermachol

2016 · Ramesh Samineni, Pabbaraja Srihari, et al. · Organic Letters · 68

New Hindered Amide Base for Aryne Insertion into Si–P, Si–S, Si–N, and C–C Bonds

2018 · Milad Mesgar, Justin Nguyen-Le, et al. · Journal of the American Chemical Society · 67

Formal Total Synthesis of (±)-Cephalotaxine and Congeners via Aryne Insertion Reaction

2016 · Pashikanti Gouthami, Rambabu Chegondi, et al. · Organic Letters · 65

Insertion of Arynes into N-Halo Bonds: A Direct Approach to o-Haloaminoarenes

2013 · Charles E. Hendrick, Stacey L. McDonald, et al. · Organic Letters · 65

Aryne Insertion into σ Bonds

2017 · Manjoorahmed Asamdi, Kishor H. Chikhalia · Asian Journal of Organic Chemistry · 60

Multiple Aryne Insertions into Oxindoles: Synthesis of Bioactive 3,3-Diarylated Oxindoles and Dibenzo[ b , e ]azepin-6-ones

2016 · Ramesh Samineni, Chandramohan Reddy C. Bandi, et al. · Organic Letters · 55

Highly Selective Insertion of Arynes into a C(sp)−O(sp3) σ Bond

2011 · Krzysztof Z. Ła̧czkowski, Diego García, et al. · Organic Letters · 55

Spiroannulation of Oxindoles via Aryne and Alkyne Incorporation: Substituent-Diverted, Transition-Metal-Free, One-Pot Access to Spirooxindoles

2017 · Ramesh Samineni, Jaipal Madapa, et al. · Organic Letters · 48

Arynes Double Bond Insertion/Nucleophilic Addition with Vinylogous Amides and Carbodiimides

2014 · Ran Li, Huarong Tang, et al. · The Journal of Organic Chemistry · 45

Synthesis of ortho-Haloaminoarenes by Aryne Insertion of Nitrogen–Halide Bonds

2014 · Charles E. Hendrick, Qiu Wang · The Journal of Organic Chemistry · 44

Annulation of Benzamides with Arynes Using Palladium with Photoredox Dual Catalysis

2019 · Jie Zhao, Hongji Li, et al. · The Journal of Organic Chemistry · 37

Works count: 97

Citation count: 2,509