Keyword

BINAP

Description: A chiral diphosphine ligand used in asymmetric catalysis, especially in transition-metal-catalyzed reactions in organic chemistry.

Primary topic: Asymmetric Hydrogenation and Catalysis (29%)

Wikidata ID: wiki/Q795991

OpenAlex ID: keywords/binap

Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones

2001 · Ryoji Noyori, Takeshi Ohkuma · Angewandte Chemie International Edition · 1,989

PDF

BINAP: an efficient chiral element for asymmetric catalysis

1990 · Ryoji Noyori, Hidemasa Takaya · Accounts of Chemical Research · 1,323

Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids

1980 · A. Miyashita, A. Yasuda, et al. · Journal of the American Chemical Society · 1,023

Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes

2003 · Christian A. Sandoval, Takeshi Ohkuma, et al. · Journal of the American Chemical Society · 628

Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions

2009 · Mandy-Nicole Birkholz (née Gensow), Zoraida Freixa, et al. · Chemical Society Reviews · 586

Recent Developments in Asymmetric Organocatalytic Domino Reactions

2012 · Hélène Pellissier · Advanced Synthesis & Catalysis · 582

Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones

2000 · Joseph M. Fox, Xiaohua Huang, et al. · Journal of the American Chemical Society · 526

Modified BINAP: The How and the Why

2005 · Mikaël Berthod, Gérard Mignani, et al. · Chemical Reviews · 516

Mechanism of the Hydrogenation of Ketones Catalyzed by trans-Dihydrido(diamine)ruthenium(II) Complexes

2002 · Kamaluddin Abdur-Rashid, Sean E. Clapham, et al. · Journal of the American Chemical Society · 510

Recent Advances in Metal-Catalyzed Asymmetric Conjugate Additions

2007 · Jens Christoffers, Girish Koripelly, et al. · Synthesis · 446

Scope and Limitations of the Pd/BINAP-Catalyzed Amination of Aryl Bromides

2000 · John P. Wolfe, Stephen L. Buchwald · The Journal of Organic Chemistry · 438

Synthesis and Applications of Binaphthylic C2-Symmetry Derivatives as Chiral Auxiliaries in Enantioselective Reactions

1992 · Carlo Rosini, Livia Franzini, et al. · Synthesis · 430

Practical synthesis of (R)- or (S)-2,2'-bis(diarylphosphino)-1,1'-binaphthyls (BINAPs)

1986 · Hidemasa Takaya, Kazushi Mashima, et al. · The Journal of Organic Chemistry · 371

Catalytic Non‐Enzymatic Kinetic Resolution

2011 · Hélène Pellissier · Advanced Synthesis & Catalysis · 353

Asymmetric hydrogenation of unsaturated carboxylic acids catalyzed by BINAP-ruthenium(II) complexes

1987 · Tetsuo Ohta, Hidemasa Takaya, et al. · The Journal of Organic Chemistry · 349

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals

2015 · Pauline Loxq, Eric Manoury, et al. · Coordination Chemistry Reviews · 347

Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of .alpha.- and .beta.-Functionalized Ketones

1994 · Kazushi Mashima, Koh-hei Kusano, et al. · The Journal of Organic Chemistry · 333

Enantioselective Tandem O-Nitroso Aldol/Michael Reaction

2004 · Yuhei Yamamoto, Norie Momiyama, et al. · Journal of the American Chemical Society · 331

trans-RuH(η-BH4)(binap)(1,2-diamine): A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions

2002 · Takeshi Ohkuma, Masatoshi Koizumi, et al. · Journal of the American Chemical Society · 308

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

2008 · In Su Kim, Ming-Yu Ngai, et al. · Journal of the American Chemical Society · 295

Carbon−Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity

2004 · Darcy A. Culkin, John F. Hartwig · Organometallics · 285

A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis

1999 · Seble Wagaw, Bryant H. Yang, et al. · Journal of the American Chemical Society · 280

Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis

2014 · Joseph M. Falkowski, Takahiro Sawano, et al. · Journal of the American Chemical Society · 274

Generation of Tertiary Phosphine-Coordinated Pd(0) Species from Pd(OAc)2 in the Catalytic Heck Reaction

1992 · Fumiyuki Ozawa, Akihiko Kubo, et al. · Chemistry Letters · 274

Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis

2020 · Andrew L. Clevenger, Ryan M. Stolley, et al. · Chemical Reviews · 259

Works count: 1,256

Citation count: 48,390