Keyword

endo selectivity

Description: The preference in a chemical reaction for forming a product with endo rather than exo stereochemistry, especially in cycloadditions.

Primary topic: Organic Chemistry Cycloaddition Reactions (38%)

OpenAlex ID: keywords/endo-selectivity

Metal‐Free, Noncovalent Catalysis of Diels–Alder Reactions by Neutral Hydrogen Bond Donors in Organic Solvents and in Water

2003 · Alexander Wittkopp, Peter R. Schreiner · Chemistry - A European Journal · 414

Selective diels-alder reactions in aqueous solutions and suspensions

1983 · Ronald Breslow, Uday Maitra, et al. · Tetrahedron Letters · 377

Intramolecular Hydroarylation of Alkynes Catalyzed by Platinum or Gold: Mechanism and endo Selectivity

2005 · Cristina Nevado, Antonio M. Echavarren · Chemistry - A European Journal · 309

The role of hydrogen bonding in controlling the selectivity of Diels–Alder reactions in room-temperature ionic liquids

2002 · Ajay Aggarwal, N. Llewellyn Lancaster, et al. · Green Chemistry · 295

Catalytic Asymmetric Inverse-Electron-Demand Diels−Alder Reaction of N-Sulfonyl-1-Aza-1,3-Dienes

2007 · Jorge Esquivias, Ramón Gómez Arrayás, et al. · Journal of the American Chemical Society · 187

Diels-Alder reactions in chloroaluminate ionic liquids: acceleration and selectivity enhancement

1999 · Carlos W. Lee · Tetrahedron Letters · 187

Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids

2014 · Yusuke Yasu, Yusuke Arai, et al. · Organic Letters · 182

Highly Diastereo- and Enantioselective Cu-Catalyzed [3 + 3] Cycloaddition of Propargyl Esters with Cyclic Enamines toward Chiral Bicyclo[ n .3.1] Frameworks

2012 · Cheng Zhang, Xin-Hu Hu, et al. · Journal of the American Chemical Society · 179

Highly Endo-Selective and Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylide with α-Enones Catalyzed by a Silver(I)/ThioClickFerrophos Complex

2010 · Ichiro Oura, Kenta Shimizu, et al. · Organic Letters · 153

PyBidine–Cu(OTf)2‐Catalyzed Asymmetric [3+2] Cycloaddition with Imino Esters: Harmony of Cu–Lewis Acid and Imidazolidine‐NH Hydrogen Bonding in Concerto Catalysis

2014 · Takayoshi Arai, Hiroki Ogawa, et al. · Angewandte Chemie International Edition · 148

Influence of Reactant Polarity on the Course of the Inverse-Electron-Demand Diels−Alder Reaction. A DFT Study of Regio- and Stereoselectivity, Presence of Lewis Acid Catalyst, and Inclusion of Solvent Effects in the Reaction between Nitroethene and Substituted Ethenes

1999 · Luis R. Domingo, Manuel Arnó, et al. · The Journal of Organic Chemistry · 147

Control of Diastereo- and Enantioselectivity in Metal-Catalyzed 1,3-Dipolar Cycloaddition Reactions of Nitrones with Alkenes. Experimental and Theoretical Investigations

1996 · Kurt V. Gothelf, Rita G. Hazell, et al. · The Journal of Organic Chemistry · 146

exo‐Selective Asymmetric Diels–Alder Reaction of 2,4‐Dienals and Nitroalkenes by Trienamine Catalysis

2011 · Zhi‐Jun Jia, Quan Zhou, et al. · Angewandte Chemie International Edition · 142

Total Synthesis of Natural Products with Bridged Bicyclo[m.n.1] Ring Systems via Type II [5 + 2] Cycloaddition

2020 · Long Min, Xin Liu, et al. · Accounts of Chemical Research · 130

Optically Active Axially Chiral Anilide and Maleimide Derivatives as New Chiral Reagents: Synthesis and Application to Asymmetric Diels−Alder Reaction

1998 · Osamu Kitagawa, Hirotaka Izawa, et al. · The Journal of Organic Chemistry · 127

Converting exo-Selective Diels−Alder Reaction to endo-Selective in Chloroloaluminate Ionic Liquids

2004 · Anil Kumar, Sanjay S. Pawar · The Journal of Organic Chemistry · 125

Density Functional Theory Study of a Lewis Acid Catalyzed Diels−Alder Reaction. The Butadiene + Acrolein Paradigm

1998 · J. I. García, V. Martínez-Merino, et al. · Journal of the American Chemical Society · 125

Highly Endo- and Enantioselective Asymmetric Nitrone Cycloadditions Catalyzed by the Aqua Complex of 4,6-Dibenzofurandiyl-2,2‘-bis(4-phenyl- oxazoline)−Nickel(II) Perchlorate. Transition Structure Based on Dramatic Effect of MS 4A on Selectivities

1998 · Shuji Kanemasa, Yoji Oderaotoshi, et al. · Journal of the American Chemical Society · 124

Radical-initiated polyolefinic cyclizations in linear triquinane synthesis. model studies and total synthesis of (±)-hirsutene

1985 · Dennis P. Curranl, Donna M. Rakiewicz · Tetrahedron · 123

Stereochemical Study on 1,3-Dipolar Cycloaddition Reactions of Heteroaromatic N-Ylides with Symmetrically Substituted cis and trans Olefins

1985 · Otohiko Tsuge, Shuji Kanemasa, et al. · Bulletin of the Chemical Society of Japan · 122

Endo selectivities of some methyl-substituted dienophiles in Diels-Alder reactions with cyclopentadiene

1970 · Junji Furukawa, Yoshiaki Kobuke, et al. · Journal of the American Chemical Society · 115

Regio- and Enantioselective Cyclization of Epoxy Alcohols Catalyzed by a [CoIII(salen)] Complex

1999 · Michael H. Wu, Karl B. Hansen, et al. · Angewandte Chemie International Edition · 112

Copper‐Catalyzed Intramolecular Electrophilic Carbofunctionalization of Allylic Amides

2013 · Elise Cahard, Nadine Bremeyer, et al. · Angewandte Chemie International Edition · 110

Endo-Selective Cyclization Pathways in the Intramolecular Heck Reaction

1995 · James H. Rigby, Robert C. Hughes, et al. · Journal of the American Chemical Society · 109

Nitrone Cycloadditions of 1,2-Cyclohexadiene

2016 · Joyann S. Barber, Evan D. Styduhar, et al. · Journal of the American Chemical Society · 108

Works count: 737

Citation count: 16,920