Keyword

model-free kinetics

Description: An approach to analyzing reaction rates without assuming a specific kinetic model, commonly used in thermal analysis of materials.

Primary topic: Thermal and Kinetic Analysis (56%)

OpenAlex ID: keywords/isoconversional-methods

ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data

2011 · Sergey Vyazovkin, Alan K. Burnham, et al. · Thermochimica Acta · 5,971

Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review

2017 · Shurong Wang, Gongxin Dai, et al. · Progress in Energy and Combustion Science · 2,602

The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods

2003 · M.J Starink · Thermochimica Acta · 1,941

Model-free and model-fitting approaches to kinetic analysis of isothermal and nonisothermal data

1999 · Sergey Vyazovkin, Charles A Wight · Thermochimica Acta · 1,418

Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies

2011 · John E. White, W. James Catallo, et al. · Journal of Analytical and Applied Pyrolysis · 1,235

Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers

2006 · Sergey Vyazovkin, Nicolas Sbirrazzuoli · Macromolecular Rapid Communications · 1,117

ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics

2020 · Sergey Vyazovkin, Alan K. Burnham, et al. · Thermochimica Acta · 1,000

Computational aspects of kinetic analysis

2000 · M.E. Brown, M. Maciejewski, et al. · Thermochimica Acta · 877

Evaluation of activation energy of thermally stimulated solid-state reactions under arbitrary variation of temperature

1997 · Sergey Vyazovkin · Journal of Computational Chemistry · 838

Pyrolysis kinetics and thermal behavior of waste sawdust biomass using thermogravimetric analysis

2017 · Ranjeet Kumar Mishra, Kaustubha Mohanty · Bioresource Technology · 806

Thermal degradation behaviors of polyethylene and polypropylene. Part I: Pyrolysis kinetics and mechanisms

2010 · A. Aboulkas, K. El harfi, et al. · Energy Conversion and Management · 727

Determination of pyrolysis characteristics and kinetics of palm kernel shell using TGA–FTIR and model-free integral methods

2014 · Zhongqing Ma, Dengyu Chen, et al. · Energy Conversion and Management · 709

Linear and Nonlinear Procedures in Isoconversional Computations of the Activation Energy of Nonisothermal Reactions in Solids

1996 · Sergey Vyazovkin, David Dollimore · Journal of Chemical Information and Computer Sciences · 682

Isothermal and non-isothermal kinetics of thermally stimulated reactions of solids

1998 · Sergey Vyazovkin, Charles A. Wight · International Reviews in Physical Chemistry · 579

Isoconversional Kinetics of Thermally Stimulated Processes

2015 · Sergey Vyazovkin · Springer eBooks · 572

A unified approach to kinetic processing of nonisothermal data

1996 · Sergey Vyazovkin · International Journal of Chemical Kinetics · 545

Kinetics in Solids

1997 · S. Vyazovkin, C. A. Wight · Annual Review of Physical Chemistry · 544

Computational aspects of kinetic analysis.

2000 · Sergey Vyazovkin · Thermochimica Acta · 538

Mechanism and Kinetics of Epoxy−Amine Cure Studied by Differential Scanning Calorimetry

1996 · Sergey Vyazovkin, Nicolas Sbirrazzuoli · Macromolecules · 492

Thermal decomposition of calcite: Mechanisms of formation and textural evolution of CaO nanocrystals

2009 · C. Rodriguez-Navarro, E. Ruiz-Agudo, et al. · American Mineralogist · 485

Model-free kinetics

2006 · S Vyazovkin · Journal of Thermal Analysis and Calorimetry · 458

Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods

2017 · Xinsong Yuan, Tao He, et al. · Renewable Energy · 440

Pyrolysis characteristics and kinetics of the marine microalgae Dunaliella tertiolecta using thermogravimetric analyzer

2009 · Zou Shuping, Wu Yulong, et al. · Bioresource Technology · 412

Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk

2017 · Junmeng Cai, Di Xu, et al. · Renewable and Sustainable Energy Reviews · 406

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The isoconversional method for determination of energy of activation at constant heating rates

1983 · J. H. Flynn · Journal of Thermal Analysis and Calorimetry · 387

Works count: 3,685

Citation count: 114,300