Keyword

methyllithium

Description: Methyllithium is an organolithium chemical compound used as a strong base and nucleophilic reagent in organic synthesis.

Primary topic: Coordination Chemistry and Organometallics (27%)

Wikidata ID: wiki/Q413849

OpenAlex ID: keywords/methyllithium

The analysis of organolithium compounds

1964 · Henry Gilman, Frank K. Cartledge · Journal of Organometallic Chemistry · 394

Lithium Intercalation Compound Dramatically Influences the Electrochemical Properties of Exfoliated MoS 2

2014 · Adriano Ambrosi, Zdeněk Sofer, et al. · Small · 309

The Carbon−Lithium Electron Pair Bond in (CH3Li)n(n= 1, 2, 4)

1996 · F. Matthias Bickelhaupt, Nicolaas J. R. van Eikema Hommes, et al. · Organometallics · 306

Transition structures for additions of lithium hydride and methyllithium to ethylene and acetylene

1985 · Kendall N. Houk, Nelson G. Rondan, et al. · Journal of the American Chemical Society · 251

Die kristall- und elektronenstruktur des methyllithiums

1964 · E. Weiss, E.A.C. Lucken · Journal of Organometallic Chemistry · 232

MoS 2 exhibits stronger toxicity with increased exfoliation

2014 · Elaine Lay Khim Chng, Zdeněk Sofer, et al. · Nanoscale · 189

Titration of alkyllithiums with a simple reagent to a blue endpoint

1997 · Andrew F. Burchat, J.Michael Chong, et al. · Journal of Organometallic Chemistry · 187

Über metall-alkyl-verbindungen

1970 · E. Weiss, G. Hencken · Journal of Organometallic Chemistry · 186

New Formulas for Organozincate Chemistry

1998 · Masanobu Uchiyama, Mitsuyoshi Kameda, et al. · Journal of the American Chemical Society · 173

Synthesis of Dialkylscandium Complexes Supported by β-Diketiminato Ligands and Activation with Tris(pentafluorophenyl)borane

1999 · Lawrence W. M. Lee, Warren E. Piers, et al. · Organometallics · 160

Unusual Structure and Reactivity of a Homoleptic “Super‐Ate” Complex of Iron: Implications for Grignard Additions, Cross‐Coupling Reactions, and the Kharasch Deconjugation

2005 · Alois Fürstner, Helga Krause, et al. · Angewandte Chemie International Edition · 157

Ab initio SCF-MO calculations of methyllithium and related systems. Absence of covalent character in the carbon-lithium bonds

1976 · Andrew Streitwieser, James E. Williams, et al. · Journal of the American Chemical Society · 138

Methyllithium and its oligomers. Structural and energetic relationships

1988 · Elmar Kaufmann, Krishnan Raghavachari, et al. · Organometallics · 136

Ab initio mechanisms for the addition of methyllithium, lithium hydride, and their dimers to formaldehyde

1985 · Elmar Kaufmann, Paul v. R. Schleyer, et al. · Journal of the American Chemical Society · 130

Effect of Ligand Structure in the Bisoxazoline Mediated Asymmetric Addition of Methyllithium to Imines

2000 · Scott E. Denmark, Cory M. Stiff · The Journal of Organic Chemistry · 123

Über metallalkyl- und -arylverbindungen

1978 · Hajo Köster, Detlef Thoennes, et al. · Journal of Organometallic Chemistry · 111

Asymmetric organolithium additions to imines

1990 · Kiyoshi Tomioka, Isao Inoue, et al. · Tetrahedron Letters · 109

Preparation and properties of hexamethyltungsten

1973 · Anthony J. Shortland, Geoffrey Wilkinson · Journal of the Chemical Society Dalton Transactions · 109

Complexes with Dative Bonds between d‐ and s‐Block Metals: Synthesis and Structure of [(Cy 3 P) 2 PtBe(Cl)X] (X=Cl, Me)

2009 · Holger Braunschweig, Katrin Gruss, et al. · Angewandte Chemie International Edition · 107

Nuclear magnetic resonance study of structure and bonding in methylithium

1969 · L. Dennis McKeever, Richard Waack, et al. · Journal of the American Chemical Society · 107

(Chloromethyl) lithium in an efficient conversion of carbonyl compounds to chlorohydrins or oxiranes

1986 · Kizhakethil Mathew Sadhu, Donald S. Matteson · Tetrahedron Letters · 105

Observations on various silyl-cuprate reagents

1984 · Ian Fleming, Trevor W. Newton · Journal of the Chemical Society Perkin Transactions 1 · 102

Synthesis of Cyclopropyl Ethers and Cyclopropanols by Carbene Transfer – Acetolysis of Cyclopropyl p‐Toluenesulfonates

1968 · U. Schöllkopf · Angewandte Chemie International Edition in English · 100

Preparation of unsaturated carbohydrates. A facile synthesis of methyl 4,6-O-Benzylidene- D -hex-2-enopyranosides

1968 · R. U. Lemieux, E. Fraga, et al. · Canadian Journal of Chemistry · 96

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Preparation of methyl ketones by the sequential treatment of carboxylic acids with methyllithium and chlorotrimethylsilane

1983 · George M. Rubottom, Chongwan Kim · The Journal of Organic Chemistry · 95

Works count: 1,844

Citation count: 23,480