Keyword

model complexes

Description: Synthetic chemical complexes designed to reproduce structural or functional features of metal-containing enzymes and their active sites.

Primary topic: Metal-Catalyzed Oxygenation Mechanisms (35%)

OpenAlex ID: keywords/model-complexes

Benchmark database of accurate (MP2 and CCSD(T) complete basis set limit) interaction energies of small model complexes, DNA base pairs, and amino acid pairs

2006 · Petr Jurečka, Jiří Šponer, et al. · Physical Chemistry Chemical Physics · 1,853

Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes. 2. Refined distances and other enzymes

1993 · Wentian Liu, H. Holden Thorp · Inorganic Chemistry · 792

The Active Sites in Manganese‐Containing Metalloproteins and Inorganic Model Complexes

1989 · Karl Wieghardt · Angewandte Chemie International Edition in English · 710

Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures

2016 · Mohammad Mahdi Najafpour, Gernot Renger, et al. · Chemical Reviews · 653

A new model for dioxygen binding in hemocyanin. Synthesis, characterization, and molecular structure of the .mu.-.eta.2:.eta.2 peroxo dinuclear copper(II) complexes, [Cu(HB(3,5-R2pz)3)]2(O2) (R = isopropyl and Ph)

1992 · Nobumasa Kitajima, Kiyoshi Fujisawa, et al. · Journal of the American Chemical Society · 641

Copper—A “Modern” Bioelement

1996 · Wolfgang Kaim, Jochen Rall · Angewandte Chemie International Edition in English · 494

Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

2018 · Andrew J. Jasniewski, Lawrence Que · Chemical Reviews · 475

Describing Noncovalent Interactions beyond the Common Approximations: How Accurate Is the “Gold Standard,” CCSD(T) at the Complete Basis Set Limit?

2013 · Jan Řezáč, Pavel Hobza · Journal of Chemical Theory and Computation · 467

Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes

1992 · H. Holden Thorp · Inorganic Chemistry · 423

Models for Nonheme Iron Intermediates: Structural Basis for Tuning the Spin States of Fe(TPA) Complexes

1997 · Yan Zang, Jinheung Kim, et al. · Journal of the American Chemical Society · 329

Understanding the copper–phenoxyl radical array in galactose oxidase: contributions from synthetic modeling studies

2000 · Brian A. Jazdzewski, William B. Tolman · Coordination Chemistry Reviews · 305

Oxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes

2016 · Xenia Engelmann, Inés Monte‐Pérez, et al. · Angewandte Chemie International Edition · 300

Coordination chemistry of microbial iron transport compounds. 19. Stability constants and electrochemical behavior of ferric enterobactin and model complexes

1979 · Wesley R. Harris, Carl J. Carrano, et al. · Journal of the American Chemical Society · 289

The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity

2021 · Nicolai Lehnert, Eunsuk Kim, et al. · Chemical Reviews · 280

Structural and functional models of nitrile hydratase

2002 · Pradip K Mascharak · Coordination Chemistry Reviews · 275

Cooperativity in multiple unusual weak bonds

2009 · Ibon Alkorta, Fernando Blanco, et al. · Theoretical Chemistry Accounts · 269

A Thiolate-Ligated Nonheme Oxoiron(IV) Complex Relevant to Cytochrome P450

2005 · Michael R. Bukowski, Kevin D. Koehntop, et al. · Science · 267

Electronic structure and reactivity of high-valent oxo iron porphyrins

2002 · Hiroshi Fujii · Coordination Chemistry Reviews · 252

High-valent oxomanganese clusters: structural and mechanistic work relevant to the oxygen-evolving center in photosystem II

1995 · Rajesh Manchanda, Gary W. Brudvig, et al. · Coordination Chemistry Reviews · 245

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Switching the Redox Mechanism: Models for Proton-Coupled Electron Transfer from Tyrosine and Tryptophan

2005 · Martin Sjödin, Stenbjörn Styring, et al. · Journal of the American Chemical Society · 241

Activation of dioxygen by copper metalloproteins and insights from model complexes

2016 · David A. Quist, Daniel E. Diaz, et al. · JBIC Journal of Biological Inorganic Chemistry · 235

Choice of Coordination Number in d 10 Complexes of Group 11 Metals

2004 · M. Angels Carvajal, Juan J. Novoa, et al. · Journal of the American Chemical Society · 228

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

2008 · Bryan E. Barton, Matthew T. Olsen, et al. · Journal of the American Chemical Society · 211

High‐Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]‐Hydrogenase Active Site

2009 · Daniel Streich, Yeni Astuti, et al. · Chemistry - A European Journal · 210

Ten Years of a Biomimetic Approach to the Copper(II) Radical Site of Galactose Oxidase

2007 · Fabrice Thomas · European Journal of Inorganic Chemistry · 209

Works count: 1,344

Citation count: 37,170