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Keyword

nitrene insertion

Description: Nitrene insertion is an organic reaction in which a nitrene species forms bonds within an existing bond, often functionalizing carbon–hydrogen bonds.
OpenAlex ID: keywords/nitrene-insertion
Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions
2010 · Hongjian Lu, X. Peter Zhang · Chemical Society Reviews · 678
Intermolecular Amidation of Unactivated sp2 and sp3 C−H Bonds via Palladium-Catalyzed Cascade C−H Activation/Nitrene Insertion
2006 · Hung-Yat Thu, Wing-Yiu Yu, et al. · Journal of the American Chemical Society · 673
Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts
2018 · Seung Youn Hong, Yoonsu Park, et al. · Science · 396
Copper–Nitrene Complexes in Catalytic CH Amination
2008 · Yosra M. Badiei, Adriana Dinescu, et al. · Angewandte Chemie International Edition · 351
Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O 2 Model Systems to Organometallic Transformations
2019 · Rachel Trammell, Khashayar Rajabimoghadam, et al. · Chemical Reviews · 298
Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes
2020 · Kaj M. van Vliet, Bas de Bruin · ACS Catalysis · 260
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Rhodium(II)‐Catalyzed CH Insertions with {[(4‐Nitrophenyl)sulfonyl]imino}phenyl‐λ3‐iodane
1997 · Ivo Nägeli, Corine Baud, et al. · Helvetica Chimica Acta · 237
Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)
2009 · Hongjian Lu, Velusamy Subbarayan, et al. · Organometallics · 188
Chemoselective, Enzymatic C–H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor
2017 · Paweł Dydio, Hanna M. Key, et al. · Journal of the American Chemical Society · 181
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Gold(III)-Catalyzed Nitrene Insertion into Aromatic and Benzylic C−H Groups
2007 · Zigang Li, David A. Capretto, et al. · Journal of the American Chemical Society · 179
Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst Tp Br3 Cu(NCMe)
2003 · M. Mar Díaz-Requejo, Tomás R. Belderraín, et al. · Journal of the American Chemical Society · 168
Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules
2014 · Mingyu Yang, Bo Su, et al. · Nature Communications · 164
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Tunable, Chemoselective Amination via Silver Catalysis
2013 · Jared W. Rigoli, Cale D. Weatherly, et al. · Journal of the American Chemical Society · 143
C−H Bond Amination from a Ferrous Dipyrromethene Complex
2009 · Evan R. King, Theodore A. Betley · Inorganic Chemistry · 129
De Novo Synthesis of Troc-Protected Amines: Intermolecular Rhodium-Catalyzed C−H Amination with N-Tosyloxycarbamates
2007 · Hélène Lebel, Kim Huard · Organic Letters · 121
Challenges and opportunities for alkane functionalisation using molecular catalysts
2017 · Xinxin Tang, Xiangqing Jia, et al. · Chemical Science · 118
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The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)
2009 · Simone Fantauzzi, Emma Gallo, et al. · Chemical Communications · 116
Rh(II)-Catalyzed Intermolecular Oxidative Sulfamidation of Aldehydes: A Mild Efficient Synthesis of N-Sulfonylcarboxamides
2007 · Johann Chan, Kyle D. Baucom, et al. · Journal of the American Chemical Society · 110
Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source
2007 · Jeremiah D. Harden, Joshua V. Ruppel, et al. · Chemical Communications · 110
A DFT Study on the Mechanism of Rh2II,II‐Catalyzed Intramolecular Amidation of Carbamates
2007 · Xufeng Lin, Cunyuan Zhao, et al. · Chemistry - An Asian Journal · 105
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Intermolecular C–H Amination of Complex Molecules: Insights into the Factors Governing the Selectivity
2012 · Camille Lescot, Benjamin Darses, et al. · The Journal of Organic Chemistry · 100
Easy Alkane Catalytic Functionalization
2008 · B. Pilar Gómez-Emeterio, Juan Urbano, et al. · Organometallics · 100
Copper–Nitrene Complexes in Catalytic CH Amination
2008 · Yosra M. Badiei, Adriana Dinescu, et al. · Angewandte Chemie · 91
A convenient synthesis of anthranilic acids by Pd-catalyzed direct intermolecular ortho-C–H amidation of benzoic acids
2012 · Ka-Ho Ng, Fo-Ning Ng, et al. · Chemical Communications · 86
Formation of an iron(III)-porphyrin complex with a nitrene moiety inserted into an iron-nitrogen bond during alkene aziridination by (tosylimidoiodo)benzene catalyzed by iron(III) porphyrins
1986 · Jean Pierre. Mahy, Pierrette. Battioni, et al. · Journal of the American Chemical Society · 80
Works count: 360
Citation count: 9,540
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