Work

Reaction of 5,13-di-tert-butyl-8,16-dimethyl(2.2)metacyclophan-1-ene with dichlorocarbene.

Year: 1984

Type: article

Abstract: Treatment of 5, 13-di-tert-butyl-8, 16-dimethyl [2. 2] metacyclophan-1-ene with 50% KOH in a mixture of chloroform and benzene in the presence of tetrabutylammonium chloride as a phase transfer catalyst afforded a heptafluvenophanene and a cycloheptatrienophanene in 17% and 22% yields.

Source: Chemical and Pharmaceutical Bulletin

DOI: 10.1248/cpb.32.4220

Authors: Masashi Tashiro, Kazumasa Kobayashi, Takehiko Yamato, Kunitoshi Yoshihira, Kayoko Kawazoe, Sadao Sato, Chihiro Tamura

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W1514909293

FWCI: 0.555

Cites:

Cited by: 1

Related to: 10